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- W2890871924 abstract "Abstract An unprecedented breaking-to-assembling methodology to synthesize the e-Fe3N nano-sheets and Fe3O4/e-Fe3N heterogeneous nano-chain bundles is reported. Specifically, the nitrided Fe aggregates with inclusions of e-Fe3N and γ′-Fe4N were electrochemically anodized without and with the assistance of the 0.4 T applied magnetic field. The corrosion of hydrochloric acid electrolyte to γ′-Fe4N breaks the large nitrided Fe aggregates into small particles with the main inclusion of e-Fe3N nanocrystals, which subsequently assemble to the large hexagonal sheets, due to the consequence of reducing the surface energy, as the anodization potential V is 15 V. Simultaneously, γ′-Fe4N was anodized to Fe3O4, especially in the case of high V value of 50 V; subsequently, Fe3O4 and e-Fe3N nanoparticles assemble to the nano-chain bundles driven by the dipole-dipole interaction. In principle, suchlike nano-sheets and nano-chain bundles can be synthesized if the nitrided metals or alloys can be corroded and simultaneously anodized in the conditions of proper eletrolyte and anodization potential. The synthesis of these nano-structures and studies on their properties and applications are in process." @default.
- W2890871924 created "2018-09-27" @default.
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- W2890871924 date "2018-12-01" @default.
- W2890871924 modified "2023-09-25" @default.
- W2890871924 title "Self-Assembly of heterogeneous nano-chain and nano-sheet through the breaking-to-assembling route" @default.
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- W2890871924 doi "https://doi.org/10.1016/j.ceramint.2018.09.053" @default.
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