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- W2890891069 abstract "Lewis acid catalyzed silyl‐Prins/alkyne‐Prins reactions are utilized for the stereoselective synthesis of 1,2‐annulated sugars having substituted tetrahydropyran (or tetrahydrofuran) scaffolds from appropriately substituted sugar derived alkenyl (or alkynyl) alcohols. These annulated molecules having stereochemical/substitution dispositions similar to those of marine toxins such as maitotoxin could act as useful building blocks for the synthesis of these natural products. Further, the utility of the silyl‐Prins reaction is extended to the synthesis of cis ‐sugar fused 4 H ‐naptho[1,2‐ b ]pyran and cis ‐sugar fused pyrano[3,2‐ c ][1]benzopyran derivatives." @default.
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- W2890891069 date "2018-11-12" @default.
- W2890891069 modified "2023-10-01" @default.
- W2890891069 title "Stereoselective Synthesis of 1,2-Annulated Sugars Having Substituted Tetrahydropyran/(-furan) Scaffolds Using the Prins-Reaction" @default.
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- W2890891069 doi "https://doi.org/10.1002/ejoc.201801273" @default.
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