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- W2890891900 abstract "A Pd/C‐catalyzed cascade approach for the synthesis of attractive benzo‐fused tropanes was developed. The reaction proceeds through a sequential Pd/C‐catalyzed dehydrogenative formation of azomethine ylides from amines and 1,3‐dipolar cycloaddition. It allows the generation of structurally complex benzo‐fused tropanes in good yields with excellent diastereoselectivities under mild reaction conditions. Preliminary results of asymmetric version of the reaction reveal that the copper catalyst and chiral monophosphoramidite ligand can furnish optically active products with moderate ee ." @default.
- W2890891900 created "2018-09-27" @default.
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- W2890891900 date "2018-10-10" @default.
- W2890891900 modified "2023-10-14" @default.
- W2890891900 title "Pd/C-Catalyzed Dehydrogenative [3+2] Cycloaddition for the Synthesis of Functionalized Tropanes" @default.
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- W2890891900 doi "https://doi.org/10.1002/ejoc.201801147" @default.
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