Matches in SemOpenAlex for { <https://semopenalex.org/work/W2890904188> ?p ?o ?g. }
- W2890904188 endingPage "5584" @default.
- W2890904188 startingPage "5570" @default.
- W2890904188 abstract "The synthesis of a single diastereomer of 3‐acetoxy‐2‐(trifluoromethyl)‐4‐hydroxy‐3,4‐dihydro‐2 H ‐thiopyran from the mixture of diastereomeric cycloadducts of p ‐tolyl trifluorodithioacetate and 1‐acetoxybutadiene is described. Its acetylation and nucleophilic chlorination provides glycosylating agents with different leaving groups have been prepared. Their reactions with various O ‐, S ‐, N ‐ and C ‐nucleophiles have been studied. Depending on the conditions of the experiments, the reactions proceed as Ferrier (I) reactions affording 3‐acetoxy‐2‐(trifluoromethyl)‐6‐substituted‐3,6‐dihydro‐2 H ‐thiopyrans or as formal direct replacement of the leaving group in the position 4 giving 3‐acetoxy‐2‐(trifluoromethyl)‐4‐substituted‐3,4‐dihydro‐2 H ‐thiopyrans. The stereochemistry of the resulting products and all their precursors is discussed." @default.
- W2890904188 created "2018-09-27" @default.
- W2890904188 creator A5005099012 @default.
- W2890904188 creator A5022767832 @default.
- W2890904188 creator A5030079169 @default.
- W2890904188 creator A5049750010 @default.
- W2890904188 creator A5059495006 @default.
- W2890904188 date "2018-09-26" @default.
- W2890904188 modified "2023-09-26" @default.
- W2890904188 title "Trifluoromethylated Thiopyranoid Glycals: Synthesis and Ferrier (I) Type Reactions" @default.
- W2890904188 cites W1969360633 @default.
- W2890904188 cites W1982414593 @default.
- W2890904188 cites W1982976078 @default.
- W2890904188 cites W1983742507 @default.
- W2890904188 cites W1986361478 @default.
- W2890904188 cites W1992442234 @default.
- W2890904188 cites W1998076335 @default.
- W2890904188 cites W2005880487 @default.
- W2890904188 cites W2012132453 @default.
- W2890904188 cites W2014050947 @default.
- W2890904188 cites W2016142547 @default.
- W2890904188 cites W2018202609 @default.
- W2890904188 cites W2020204270 @default.
- W2890904188 cites W2024100777 @default.
- W2890904188 cites W2025443227 @default.
- W2890904188 cites W2031878333 @default.
- W2890904188 cites W2039169670 @default.
- W2890904188 cites W2044583023 @default.
- W2890904188 cites W2047449212 @default.
- W2890904188 cites W2053072291 @default.
- W2890904188 cites W2054418050 @default.
- W2890904188 cites W2056619676 @default.
- W2890904188 cites W2061693970 @default.
- W2890904188 cites W2066191837 @default.
- W2890904188 cites W2068663539 @default.
- W2890904188 cites W2082953126 @default.
- W2890904188 cites W2090805069 @default.
- W2890904188 cites W2094720373 @default.
- W2890904188 cites W2094947247 @default.
- W2890904188 cites W2098542017 @default.
- W2890904188 cites W2132454074 @default.
- W2890904188 cites W2132950534 @default.
- W2890904188 cites W2135675956 @default.
- W2890904188 cites W2147909434 @default.
- W2890904188 cites W2148736616 @default.
- W2890904188 cites W2163676110 @default.
- W2890904188 cites W2172087043 @default.
- W2890904188 cites W2325401617 @default.
- W2890904188 cites W2335511005 @default.
- W2890904188 cites W2419074301 @default.
- W2890904188 cites W2491309875 @default.
- W2890904188 cites W2555964756 @default.
- W2890904188 cites W2949304883 @default.
- W2890904188 cites W2949566145 @default.
- W2890904188 cites W2949971679 @default.
- W2890904188 cites W2951667345 @default.
- W2890904188 cites W2952690731 @default.
- W2890904188 cites W4239366580 @default.
- W2890904188 doi "https://doi.org/10.1002/ejoc.201800643" @default.
- W2890904188 hasPublicationYear "2018" @default.
- W2890904188 type Work @default.
- W2890904188 sameAs 2890904188 @default.
- W2890904188 citedByCount "4" @default.
- W2890904188 countsByYear W28909041882020 @default.
- W2890904188 countsByYear W28909041882021 @default.
- W2890904188 countsByYear W28909041882022 @default.
- W2890904188 crossrefType "journal-article" @default.
- W2890904188 hasAuthorship W2890904188A5005099012 @default.
- W2890904188 hasAuthorship W2890904188A5022767832 @default.
- W2890904188 hasAuthorship W2890904188A5030079169 @default.
- W2890904188 hasAuthorship W2890904188A5049750010 @default.
- W2890904188 hasAuthorship W2890904188A5059495006 @default.
- W2890904188 hasConcept C138716334 @default.
- W2890904188 hasConcept C155647269 @default.
- W2890904188 hasConcept C161790260 @default.
- W2890904188 hasConcept C178790620 @default.
- W2890904188 hasConcept C178907741 @default.
- W2890904188 hasConcept C185592680 @default.
- W2890904188 hasConcept C20774148 @default.
- W2890904188 hasConcept C2776442012 @default.
- W2890904188 hasConcept C2780263894 @default.
- W2890904188 hasConcept C50027330 @default.
- W2890904188 hasConcept C71240020 @default.
- W2890904188 hasConceptScore W2890904188C138716334 @default.
- W2890904188 hasConceptScore W2890904188C155647269 @default.
- W2890904188 hasConceptScore W2890904188C161790260 @default.
- W2890904188 hasConceptScore W2890904188C178790620 @default.
- W2890904188 hasConceptScore W2890904188C178907741 @default.
- W2890904188 hasConceptScore W2890904188C185592680 @default.
- W2890904188 hasConceptScore W2890904188C20774148 @default.
- W2890904188 hasConceptScore W2890904188C2776442012 @default.
- W2890904188 hasConceptScore W2890904188C2780263894 @default.
- W2890904188 hasConceptScore W2890904188C50027330 @default.
- W2890904188 hasConceptScore W2890904188C71240020 @default.
- W2890904188 hasIssue "40" @default.
- W2890904188 hasLocation W28909041881 @default.
- W2890904188 hasOpenAccess W2890904188 @default.
- W2890904188 hasPrimaryLocation W28909041881 @default.