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- W2890904474 abstract "Zwitterionic structure is necessary for NiII complexes to catalyze carbonylative polymerization (COP) of cyclic ethers. The cationic charge at the NiII center imparts sufficient electrophilicity to the Ni-acyl bond for it to react with cyclic ethers to give an acyl-cyclic ether oxonium intermediate, while the ligand-centered anionic charge ensures that the resultant oxonium cation is ion-paired with the Ni0 nucleophile. The current catalysts give non-alternating copolymers of carbon monoxide and cyclic ethers and are the most effective when both ethylene oxide and tetrahydrofuran are present as the cyclic ether monomers." @default.
- W2890904474 created "2018-09-27" @default.
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- W2890904474 date "2018-10-02" @default.
- W2890904474 modified "2023-09-24" @default.
- W2890904474 title "Zwitterionic Design Principle of Nickel(II) Catalysts for Carbonylative Polymerization of Cyclic Ethers" @default.
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- W2890904474 doi "https://doi.org/10.1002/anie.201808507" @default.
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