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• W2890906968 abstract "A new generation-2 light-responsive metal–organic framework (MOF) has been successfully synthesized using Zn as the metal source and both 2-phenyldiazenyl terephthalic acid and 1,4-diazabicyclo[2.2.2]octane (DABCO) as the ligands. It was found that Zn-azo-dabco MOF (Azo-DMOF-1) exhibited a photoresponsive CO2 adsorption both in static and dynamic condition because of the presence of azobenzene functionalities from the ligand. Further application of this MOF was evaluated by incorporating it as a filler in a mixed matrix membrane for CO2/N2 gas separation. Matrimid and polymer of intrinsic microporosity-1 (PIM-1) were used as the polymer matrix. It was found that Azo-DMOF-1 could enhance both the CO2 permeability and selectivity of the pristine polymer. In particular, the Azo-DMOF-1–PIM-1 composite membranes have shown a promising performance that surpassed the 2008 Robeson Upper Bound." @default.
• W2890906968 created "2018-09-27" @default.
• W2890906968 creator A5017703665 @default.
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• W2890906968 date "2018-09-11" @default.
• W2890906968 modified "2023-10-06" @default.
• W2890906968 title "New Azo-DMOF-1 MOF as a Photoresponsive Low-Energy CO₂ Adsorbent and Its Exceptional CO₂/N₂ Separation Performance in Mixed Matrix Membranes" @default.
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• W2890906968 doi "https://doi.org/10.1021/acsami.8b12261" @default.
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• W2890906968 hasPublicationYear "2018" @default.
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