Matches in SemOpenAlex for { <https://semopenalex.org/work/W2890912281> ?p ?o ?g. }
- W2890912281 endingPage "10020" @default.
- W2890912281 startingPage "10012" @default.
- W2890912281 abstract "The CO2 electroreduction reaction (CO2RR) to chemicals and fuels is of both fundamental and practical significance, since it would lead to a more efficient storage of renewable energy while closing the carbon cycle. Here we report enhanced activity and selectivity for the CO2RR to multicarbon hydrocarbons and alcohols (∼69% Faradaic efficiency and −45.5 mA cm–2 partial current density for C2+ at −1.0 V vs RHE) over O2-plasma-activated Cu catalysts via electrolyte design. Increasing the size of the alkali-metal cations in the electrolyte, in combination with the presence of subsurface oxygen species which favor their adsorption, significantly improved C–C coupling on CuOx electrodes. The coexistence of Cs+ and I– induced drastic restructuring of the CuOx surface, the formation of shaped particles containing stable CuI species, and a more favorable stabilization of the reaction intermediates and concomitant high C2+ selectivity. This work, combining both experiment and density functional theory, provides in..." @default.
- W2890912281 created "2018-09-27" @default.
- W2890912281 creator A5001110833 @default.
- W2890912281 creator A5031735060 @default.
- W2890912281 creator A5034358731 @default.
- W2890912281 creator A5049616422 @default.
- W2890912281 creator A5055823801 @default.
- W2890912281 creator A5057674638 @default.
- W2890912281 creator A5065326930 @default.
- W2890912281 creator A5072838762 @default.
- W2890912281 creator A5086719406 @default.
- W2890912281 date "2018-09-11" @default.
- W2890912281 modified "2023-10-17" @default.
- W2890912281 title "Activity and Selectivity Control in CO<sub>2</sub> Electroreduction to Multicarbon Products over CuO<sub><i>x</i></sub> Catalysts via Electrolyte Design" @default.
- W2890912281 cites W1970127494 @default.
- W2890912281 cites W1973634181 @default.
- W2890912281 cites W1975526738 @default.
- W2890912281 cites W1979544533 @default.
- W2890912281 cites W1995765480 @default.
- W2890912281 cites W2007395042 @default.
- W2890912281 cites W2036113194 @default.
- W2890912281 cites W2054121315 @default.
- W2890912281 cites W2057499499 @default.
- W2890912281 cites W2060023027 @default.
- W2890912281 cites W2070161787 @default.
- W2890912281 cites W2073580180 @default.
- W2890912281 cites W2074964984 @default.
- W2890912281 cites W2083222334 @default.
- W2890912281 cites W2091135029 @default.
- W2890912281 cites W2144904466 @default.
- W2890912281 cites W2170456486 @default.
- W2890912281 cites W2234779942 @default.
- W2890912281 cites W2275870655 @default.
- W2890912281 cites W228629631 @default.
- W2890912281 cites W2294789198 @default.
- W2890912281 cites W2314642759 @default.
- W2890912281 cites W2319865050 @default.
- W2890912281 cites W2323309348 @default.
- W2890912281 cites W2336845479 @default.
- W2890912281 cites W2338294784 @default.
- W2890912281 cites W2470552650 @default.
- W2890912281 cites W2515196917 @default.
- W2890912281 cites W2515773792 @default.
- W2890912281 cites W2520778196 @default.
- W2890912281 cites W2560832335 @default.
- W2890912281 cites W2561854106 @default.
- W2890912281 cites W2565135807 @default.
- W2890912281 cites W2566427279 @default.
- W2890912281 cites W2567342708 @default.
- W2890912281 cites W2569888948 @default.
- W2890912281 cites W2586083027 @default.
- W2890912281 cites W2588520044 @default.
- W2890912281 cites W2590930531 @default.
- W2890912281 cites W2608300873 @default.
- W2890912281 cites W2625339367 @default.
- W2890912281 cites W2625918461 @default.
- W2890912281 cites W2626885970 @default.
- W2890912281 cites W2698517883 @default.
- W2890912281 cites W2735052779 @default.
- W2890912281 cites W2738629485 @default.
- W2890912281 cites W2739088978 @default.
- W2890912281 cites W2740275019 @default.
- W2890912281 cites W2742615673 @default.
- W2890912281 cites W2749923946 @default.
- W2890912281 cites W2755271205 @default.
- W2890912281 cites W2765422782 @default.
- W2890912281 cites W2767138048 @default.
- W2890912281 cites W2767281273 @default.
- W2890912281 cites W2769548155 @default.
- W2890912281 cites W2782159534 @default.
- W2890912281 cites W2782968955 @default.
- W2890912281 cites W2783223040 @default.
- W2890912281 cites W2783949446 @default.
- W2890912281 cites W2793543406 @default.
- W2890912281 cites W2799882390 @default.
- W2890912281 cites W2800064336 @default.
- W2890912281 cites W2802559112 @default.
- W2890912281 cites W2804235153 @default.
- W2890912281 cites W2808940939 @default.
- W2890912281 cites W2812453445 @default.
- W2890912281 cites W2883336409 @default.
- W2890912281 cites W2884467164 @default.
- W2890912281 cites W2887595360 @default.
- W2890912281 cites W3206606417 @default.
- W2890912281 cites W4235574122 @default.
- W2890912281 doi "https://doi.org/10.1021/acscatal.8b02587" @default.
- W2890912281 hasPublicationYear "2018" @default.
- W2890912281 type Work @default.
- W2890912281 sameAs 2890912281 @default.
- W2890912281 citedByCount "148" @default.
- W2890912281 countsByYear W28909122812018 @default.
- W2890912281 countsByYear W28909122812019 @default.
- W2890912281 countsByYear W28909122812020 @default.
- W2890912281 countsByYear W28909122812021 @default.
- W2890912281 countsByYear W28909122812022 @default.
- W2890912281 countsByYear W28909122812023 @default.
- W2890912281 crossrefType "journal-article" @default.
- W2890912281 hasAuthorship W2890912281A5001110833 @default.