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- W2890928573 abstract "Abstract A Pd/C‐catalyzed domino synthesis of symmetrical and unsymmetrical ureas from aryl iodides, sodium azide, amines and CHCl 3 in water has been developed. This reaction proceeds with sequential carbonylation, Curtius rearrangement and nucleophilic addition. CHCl 3 serves as a convenient and safe alternation of CO gas in the presence of KOH. A series of urea derivatives were obtained in moderate to good yields with good functional group tolerance. Furthermore, the Pd/C catalyst could be readily recovered with slight decrease in the catalytic activity after six consecutive runs. magnified image" @default.
- W2890928573 created "2018-09-27" @default.
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- W2890928573 date "2018-10-22" @default.
- W2890928573 modified "2023-10-15" @default.
- W2890928573 title "Pd/C‐Catalyzed Domino Synthesis of Urea Derivatives Using Chloroform as the Carbon Monoxide Source in Water" @default.
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- W2890928573 doi "https://doi.org/10.1002/adsc.201800954" @default.
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