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• W2890936922 abstract "Bimetallic oxides ABOx (x = 2, 3, and 4) with multiple lattice sites have shown numerous properties, blossoming into diverse applications, while regulating the valence state at the A or B site usually causes a dramatic change in the crystal structure, giving rise to uncertainties in comprehending the structure–property relationships. Herein, we synthesized bimetallic layered crednerite CuMnO2 with double-coordinate Cu cations at the A site and hexa-coordinate Mn cations at the B site via a cetyltrimethylammonium bromide (CTAB) modified hydrothermal method. By controlling the crystal growth temperature, valence states tailoring was implemented along with the stabilization of the monoclinic layered structure. The regulation process was followed by morphology changes of the CuMnO2 crystal in a sequence: triangular sheets (140 °C), nanowires (160 °C), hexagonal prisms (180 °C), and octahedrons (over 200 °C). Interestingly, the oxidation states of Cu2+ and Mn2+ were found for triangular sheets, which transform..." @default.
• W2890936922 created "2018-09-27" @default.
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• W2890936922 date "2018-09-04" @default.
• W2890936922 modified "2023-10-17" @default.
• W2890936922 title "Crystal Growth of Bimetallic Oxides CuMnO₂ with Tailored Valence States for Optimum Electrochemical Energy Storage" @default.
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• W2890936922 doi "https://doi.org/10.1021/acs.cgd.8b00988" @default.
• W2890936922 hasPublicationYear "2018" @default.
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