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• W2890944192 abstract "Compounds such as 3, the product of a palladium[0]-catalyzed Ullmann cross-coupling of o-iodonitrobenzene and 2-iodocyclohex-2-en-1-one, undergo complementary modes of reductive cyclization depending upon the conditions employed. Thus, on treatment with hydrogen in the presence of palladium on carbon, the tetrahydrocarbazole 4 is formed, while reaction of the same substrate (3) with TiCl3 in acetone affords the 1,2,3,9-tetrahydro-4H-carbazol-4-one 6." @default.
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• W2890944192 date "2018-09-05" @default.
• W2890944192 modified "2023-10-16" @default.
• W2890944192 title "Reductive Cyclization of <i>o</i>-Nitroarylated-α,β-unsaturated Aldehydes and Ketones with TiCl₃/HCl or Fe/HCl Leading to 1,2,3,9-Tetrahydro-4<i>H</i>-carbazol-4-ones and Related Heterocycles" @default.
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• W2890944192 doi "https://doi.org/10.1021/acs.joc.8b01940" @default.
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