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- W2890956601 abstract "Abstract Rate constants for the hydrolysis reaction of phosphate (paraoxon) and thiophosphate (parathion, fenitrothion) esters by oximate (pyridinealdoxime 2‐PyOx − and 4‐PyOx − ) and its functionalized pyridinium surfactants 4‐(hydroxyimino) methyl)‐1‐alkylpyridinium bromide ions (alkyl = C n H 2 n +1 , n = 10, 12, 14, 16) have been measured kinetically at pH 9.5 and 27°C in micellar media of cationic surfactants cetyltrimethylammonium bromide (CTAB) and cetylpyridinium bromide (CPB). Acid dissociation constant, p K a , of oximes has also been determined by spectrophotometric, kinetic, and potentiometric methods. The rate acceleration effects of cationic micelles have been explored. Cationic micelles of the pyridinium head group (CPB) showed a large catalytic effect than the ammonium head group (CTAB). The effects of pH, oximate concentration, and surfactants have been discussed." @default.
- W2890956601 created "2018-09-27" @default.
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- W2890956601 date "2018-09-05" @default.
- W2890956601 modified "2023-10-09" @default.
- W2890956601 title "Micellar-accelerated hydrolysis of organophosphate and thiophosphates by pyridine oximate" @default.
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- W2890956601 doi "https://doi.org/10.1002/kin.21217" @default.
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