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- W2890981170 abstract "Abstract To probe the possibility that carbodicarbenes (CDCs) are redox active ligands, all four members of the redox series [Fe( 1 ) 2 ] n + ( n =2–5) were synthesized, where 1 is a neutral tridentate CDC. Through a combination of spectroscopy and DFT calculations, the electronic structure of the pentacation is shown to be [Fe III ( 1 .+ ) 2 ] 5+ ( S = ). That of [Fe( 1 ) 2 ] 4+ is more ambiguous, but it has significant contributions from the open‐shell singlet [Fe III ( 1 )( 1 .+ )] 4+ ( S =0). The observed spin states derive from antiferromagnetic coupling of their constituent low‐spin iron(III) centres and cation radical ligands. This marks the first time redox activity has been observed for carbones and expands the diverse chemical behaviour known for these ligands." @default.
- W2890981170 created "2018-09-27" @default.
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- W2890981170 date "2018-11-02" @default.
- W2890981170 modified "2023-10-14" @default.
- W2890981170 title "Observation of Carbodicarbene Ligand Redox Noninnocence in Highly Oxidized Iron Complexes" @default.
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- W2890981170 doi "https://doi.org/10.1002/anie.201809158" @default.
- W2890981170 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30239076" @default.
- W2890981170 hasPublicationYear "2018" @default.