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- W2890987957 abstract "The nucleotide loop in the vitamin B 12 structure affects its biological and physicochemical properties, but its role in cobalamin‐catalysed reactions still remains disputable. Herein, we show the synthesis of a series of model compounds including N ‐methylcobalamin (NMICbl) in a base‐off form with the nucleotide attached. The structure‐activity relationship studies reveal that in the studied cobalamin‐catalysed reaction, the reduction step is not rate‐determining." @default.
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- W2890987957 date "2018-10-10" @default.
- W2890987957 modified "2023-09-27" @default.
- W2890987957 title "Cobalamin‐Catalysed Chemical Reactions: Probing the Role of the Nucleotide Loop" @default.
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- W2890987957 doi "https://doi.org/10.1002/ejoc.201800877" @default.
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