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• W2890991519 startingPage "6515" @default.
• W2890991519 abstract "Herein we introduce a new guest, the guanidiniocarbonyl pyrrole cation (GCP), for host–guest chemistry with cucurbit[8]uril. Macromodel calculations as well as isothermal titration calorimetry (ITC), showed that CB[8] can entrap two GCP molecules inside its hydrophobic cavity. Using this 1:2‐complex formation, we further show that CB[8] can induce crosslinking of a flexibletetracationic guanidiniocarbonyl pyrrole. An extended supramolecular cross‐linked 3D network was observed at pH 4.1 where all GCP groups in guanidiniocarbonyl pyrrole are protonated. At pH 6.5, the GCP groups are only partially protonated nanostructures with a more globular vesicle‐like shape." @default.
• W2890991519 created "2018-09-27" @default.
• W2890991519 creator A5045043209 @default.
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• W2890991519 date "2018-11-20" @default.
• W2890991519 modified "2023-09-25" @default.
• W2890991519 title "Guanidiniocarbonyl Pyrrole Cation (GCP) - A New Guest for Cucurbit[8]uril: Application to the Synthesis of Supramolecular Polymers Based on CB[8]@2GCP Complex Formation" @default.
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• W2890991519 doi "https://doi.org/10.1002/ejoc.201801210" @default.
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