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- W2890991610 abstract "The application of the Restricted Active Space Self Consistent Field (RASSCF) quantum chemical method using an extended active space and including σ-σ, π-σ and π-π dynamical electron correlation shows that the transition state structure for the automerization reaction of cyclobutadiene is an isosceles trapezium. This transition state is obtained without any symmetry constraints. The calculated energy barrier height involving the zero point vibrational energy corrections is 9.62 kcal∙mol−1 (0.417 eV), with the corresponding rate constant being equal to 0.18 × 109 s−1 (or 7.1 × 1010 s−1 in case of using the vibrational energy splitting tunneling method)." @default.
- W2890991610 created "2018-09-27" @default.
- W2890991610 creator A5023307140 @default.
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- W2890991610 date "2018-11-01" @default.
- W2890991610 modified "2023-10-12" @default.
- W2890991610 title "The transition state of the automerization reaction of cyclobutadiene: A theoretical approach using the Restricted Active Space Self Consistent Field method" @default.
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- W2890991610 doi "https://doi.org/10.1016/j.cplett.2018.09.028" @default.
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