FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2891007986> ?p ?o ?g. }

• W2891007986 endingPage "32433" @default.
• W2891007986 startingPage "32423" @default.
• W2891007986 abstract "The efficient conversion of carbohydrates to 5-hydroxymethylfurfural (5-HMF) under mild conditions represents a very attractive and promising method of producing important building blocks. In this work, niobium phosphotungstates, with Nb/P molar ratios of 0.6, 1.0, 2.0 and 4.0 (NbPW-06, NbPW-1, NbPW-2, and NbPW-4, respectively) have been prepared by a facile, one-pot, alcohol-mediated thermal process and used for the direct conversion of fructose to 5-HMF. By adding a certain amount of Nb, the surface of the catalyst became enriched in P, and this enrichment was associated with the presence of surface P-OH groups that offered Brønsted acid sites that can activate superficial hydrogen species to facilitate 5-HMF generation. Pyridine-FTIR confirmed the presence of Brønsted and Lewis acid sites, which might play important roles in the dehydration of fructose to 5-HMF. Furthermore, polar aprotic solvents were well-suited for the conversion, and higher yields of 5-HMF were obtained in polar aprotic solvents than in nonpolar solvents. A 5-HMF yield of 96.7% with complete fructose consumption was obtained over NbPW-06 in DMSO at 80 °C after 90 min. In addition, NbPW-06 could be recycled several times without a significant decrease in the catalytic activity. A catalytic mechanism for this reaction was proposed. Moreover, this catalytic system can also be utilized for the dehydration of sucrose and inulin to 5-HMF in satisfactory yields. This study establishes an important platform for the further design of Nb-containing catalysts for the production of 5-HMF from carbohydrates under mild conditions." @default.
• W2891007986 created "2018-09-27" @default.
• W2891007986 creator A5033825187 @default.
• W2891007986 creator A5045265348 @default.
• W2891007986 creator A5059808079 @default.
• W2891007986 creator A5069915147 @default.
• W2891007986 creator A5072522625 @default.
• W2891007986 date "2018-01-01" @default.
• W2891007986 modified "2023-09-26" @default.
• W2891007986 title "Niobium phosphotungstates: excellent solid acid catalysts for the dehydration of fructose to 5-hydroxymethylfurfural under mild conditions" @default.
• W2891007986 cites W1191393725 @default.
• W2891007986 cites W1750457094 @default.
• W2891007986 cites W1835175904 @default.
• W2891007986 cites W1886212929 @default.
• W2891007986 cites W1909052161 @default.
• W2891007986 cites W1963556991 @default.
• W2891007986 cites W1967812668 @default.
• W2891007986 cites W1968392170 @default.
• W2891007986 cites W1970994153 @default.
• W2891007986 cites W1973786808 @default.
• W2891007986 cites W1992417924 @default.
• W2891007986 cites W2003129550 @default.
• W2891007986 cites W2009489922 @default.
• W2891007986 cites W2009799671 @default.
• W2891007986 cites W2011180893 @default.
• W2891007986 cites W2016391111 @default.
• W2891007986 cites W2020478730 @default.
• W2891007986 cites W2027798701 @default.
• W2891007986 cites W2029605038 @default.
• W2891007986 cites W2030273425 @default.
• W2891007986 cites W2043899178 @default.
• W2891007986 cites W2045595536 @default.
• W2891007986 cites W2048704620 @default.
• W2891007986 cites W2049863848 @default.
• W2891007986 cites W2049867379 @default.
• W2891007986 cites W2051276746 @default.
• W2891007986 cites W2053955315 @default.
• W2891007986 cites W2056966307 @default.
• W2891007986 cites W2058321979 @default.
• W2891007986 cites W2076192137 @default.
• W2891007986 cites W2083803200 @default.
• W2891007986 cites W2084726128 @default.
• W2891007986 cites W2086202007 @default.
• W2891007986 cites W2087708549 @default.
• W2891007986 cites W2098226866 @default.
• W2891007986 cites W2109566350 @default.
• W2891007986 cites W2125238649 @default.
• W2891007986 cites W2132426779 @default.
• W2891007986 cites W2133736093 @default.
• W2891007986 cites W2144613836 @default.
• W2891007986 cites W2163156526 @default.
• W2891007986 cites W2235464875 @default.
• W2891007986 cites W2278615667 @default.
• W2891007986 cites W2294955281 @default.
• W2891007986 cites W2314885267 @default.
• W2891007986 cites W2315485137 @default.
• W2891007986 cites W2316337772 @default.
• W2891007986 cites W2317414015 @default.
• W2891007986 cites W2322342266 @default.
• W2891007986 cites W2328071780 @default.
• W2891007986 cites W2338871431 @default.
• W2891007986 cites W2344873506 @default.
• W2891007986 cites W2368270449 @default.
• W2891007986 cites W2415897117 @default.
• W2891007986 cites W2460439381 @default.
• W2891007986 cites W2592709981 @default.
• W2891007986 cites W2601670513 @default.
• W2891007986 cites W2618086918 @default.
• W2891007986 cites W2735372486 @default.
• W2891007986 doi "https://doi.org/10.1039/c8ra05940c" @default.
• W2891007986 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35547663" @default.
• W2891007986 hasPublicationYear "2018" @default.
• W2891007986 type Work @default.
• W2891007986 sameAs 2891007986 @default.
• W2891007986 citedByCount "11" @default.
• W2891007986 countsByYear W28910079862018 @default.
• W2891007986 countsByYear W28910079862020 @default.
• W2891007986 countsByYear W28910079862021 @default.
• W2891007986 countsByYear W28910079862022 @default.
• W2891007986 countsByYear W28910079862023 @default.
• W2891007986 crossrefType "journal-article" @default.
• W2891007986 hasAuthorship W2891007986A5033825187 @default.
• W2891007986 hasAuthorship W2891007986A5045265348 @default.
• W2891007986 hasAuthorship W2891007986A5059808079 @default.
• W2891007986 hasAuthorship W2891007986A5069915147 @default.
• W2891007986 hasAuthorship W2891007986A5072522625 @default.
• W2891007986 hasBestOaLocation W28910079861 @default.
• W2891007986 hasConcept C134121241 @default.
• W2891007986 hasConcept C161790260 @default.
• W2891007986 hasConcept C163638829 @default.
• W2891007986 hasConcept C178790620 @default.
• W2891007986 hasConcept C185592680 @default.
• W2891007986 hasConcept C191897082 @default.
• W2891007986 hasConcept C192562407 @default.
• W2891007986 hasConcept C2776339268 @default.
• W2891007986 hasConcept C2776970464 @default.
• W2891007986 hasConcept C2778597767 @default.
• W2891007986 hasConcept C2778769901 @default.

• next