Matches in SemOpenAlex for { <https://semopenalex.org/work/W2891024823> ?p ?o ?g. }
- W2891024823 endingPage "3224" @default.
- W2891024823 startingPage "3219" @default.
- W2891024823 abstract "Hyperconjugation, an interaction of electrons in a σ orbital or lone pair with an adjacent π or even σ antibonding orbital, can have a strong effect on aromaticity. However, most work on hyperconjugative aromaticity has been limited to main-group substituents. Here, we report a thorough density functional theory study to evaluate the aromaticity in various cyclopentadienes that contain both main-group and transition-metal substituents. Our calculations reveal that the strongest aromatic cyclopentadiene ring can be achieved by the synergy of trans influence and hyperconjugation caused by transition-metal substituents. Our findings highlight the great power of transition metals and trans influence in achieving hyperconjugative aromaticity, opening an avenue to the design of other novel aromatic organometallics." @default.
- W2891024823 created "2018-09-27" @default.
- W2891024823 creator A5012980782 @default.
- W2891024823 creator A5015632170 @default.
- W2891024823 creator A5041897678 @default.
- W2891024823 date "2018-09-11" @default.
- W2891024823 modified "2023-10-17" @default.
- W2891024823 title "Probing the Strongest Aromatic Cyclopentadiene Ring by Hyperconjugation" @default.
- W2891024823 cites W1527615751 @default.
- W2891024823 cites W1940580826 @default.
- W2891024823 cites W1966356592 @default.
- W2891024823 cites W1967734332 @default.
- W2891024823 cites W1977839393 @default.
- W2891024823 cites W1981238739 @default.
- W2891024823 cites W1981745234 @default.
- W2891024823 cites W1984614201 @default.
- W2891024823 cites W1991514129 @default.
- W2891024823 cites W2019406135 @default.
- W2891024823 cites W2022366997 @default.
- W2891024823 cites W2023271753 @default.
- W2891024823 cites W2024964673 @default.
- W2891024823 cites W2032381493 @default.
- W2891024823 cites W2036390964 @default.
- W2891024823 cites W2038767330 @default.
- W2891024823 cites W2040986227 @default.
- W2891024823 cites W2047262903 @default.
- W2891024823 cites W2050893571 @default.
- W2891024823 cites W2051372059 @default.
- W2891024823 cites W2051879335 @default.
- W2891024823 cites W2053248916 @default.
- W2891024823 cites W2054678170 @default.
- W2891024823 cites W2055770627 @default.
- W2891024823 cites W2056224613 @default.
- W2891024823 cites W2058031804 @default.
- W2891024823 cites W2060768691 @default.
- W2891024823 cites W2061610215 @default.
- W2891024823 cites W2062991523 @default.
- W2891024823 cites W2066172463 @default.
- W2891024823 cites W2067570011 @default.
- W2891024823 cites W2070005238 @default.
- W2891024823 cites W2074971812 @default.
- W2891024823 cites W2079256799 @default.
- W2891024823 cites W2092157292 @default.
- W2891024823 cites W2097955572 @default.
- W2891024823 cites W2099448329 @default.
- W2891024823 cites W2100470118 @default.
- W2891024823 cites W2105189720 @default.
- W2891024823 cites W2116634991 @default.
- W2891024823 cites W2119405370 @default.
- W2891024823 cites W2122503682 @default.
- W2891024823 cites W2124501873 @default.
- W2891024823 cites W2132525235 @default.
- W2891024823 cites W2135882968 @default.
- W2891024823 cites W2143173366 @default.
- W2891024823 cites W2143981217 @default.
- W2891024823 cites W2144596014 @default.
- W2891024823 cites W2149533343 @default.
- W2891024823 cites W2150345533 @default.
- W2891024823 cites W2173230724 @default.
- W2891024823 cites W2259599737 @default.
- W2891024823 cites W2312443767 @default.
- W2891024823 cites W2312471787 @default.
- W2891024823 cites W2316548484 @default.
- W2891024823 cites W2323886211 @default.
- W2891024823 cites W2326098504 @default.
- W2891024823 cites W2328794886 @default.
- W2891024823 cites W2331619325 @default.
- W2891024823 cites W2332105809 @default.
- W2891024823 cites W2404352964 @default.
- W2891024823 cites W2527953399 @default.
- W2891024823 cites W2558200283 @default.
- W2891024823 cites W2563098883 @default.
- W2891024823 cites W2586949393 @default.
- W2891024823 cites W2617292491 @default.
- W2891024823 cites W2789834766 @default.
- W2891024823 cites W2884080304 @default.
- W2891024823 cites W2949757649 @default.
- W2891024823 cites W2950076633 @default.
- W2891024823 cites W4211042738 @default.
- W2891024823 cites W4231604039 @default.
- W2891024823 cites W4235998838 @default.
- W2891024823 doi "https://doi.org/10.1021/acs.organomet.8b00571" @default.
- W2891024823 hasPublicationYear "2018" @default.
- W2891024823 type Work @default.
- W2891024823 sameAs 2891024823 @default.
- W2891024823 citedByCount "17" @default.
- W2891024823 countsByYear W28910248232018 @default.
- W2891024823 countsByYear W28910248232019 @default.
- W2891024823 countsByYear W28910248232020 @default.
- W2891024823 countsByYear W28910248232021 @default.
- W2891024823 countsByYear W28910248232022 @default.
- W2891024823 countsByYear W28910248232023 @default.
- W2891024823 crossrefType "journal-article" @default.
- W2891024823 hasAuthorship W2891024823A5012980782 @default.
- W2891024823 hasAuthorship W2891024823A5015632170 @default.
- W2891024823 hasAuthorship W2891024823A5041897678 @default.
- W2891024823 hasConcept C121332964 @default.
- W2891024823 hasConcept C147120987 @default.