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- W2891026324 abstract "We show here the first colloidal synthesis of double perovskite Cs2AgInCl6 nanocrystals (NCs) with a control over their size distribution. In our approach, metal carboxylate precursors and ligands (oleylamine and oleic acid) are dissolved in diphenyl ether and reacted at 105 °C with benzoyl chloride. The resulting Cs2AgInCl6 NCs exhibit the expected double perovskite crystal structure, are stable under air, and show a broad spectrum white photoluminescence (PL) with quantum yield of ∼1.6 ± 1%. The optical properties of these NCs were improved by synthesizing Mn-doped Cs2AgInCl6 NCs through the simple addition of Mn-acetate to the reaction mixture. The NC products were characterized by the same double perovskite crystal structure, and Mn doping levels up to 1.5%, as confirmed by elemental analyses. The effective incorporation of Mn ions inside Cs2AgInCl6 NCs was also proved by means of electron spin resonance spectroscopy. A bright orange emission characterized our Mn-doped Cs2AgInCl6 NCs with a PL quantum yield as high as ∼16 ± 4%." @default.
- W2891026324 created "2018-09-27" @default.
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- W2891026324 date "2018-09-10" @default.
- W2891026324 modified "2023-10-14" @default.
- W2891026324 title "Colloidal Synthesis of Double Perovskite Cs<sub>2</sub>AgInCl<sub>6</sub> and Mn-Doped Cs<sub>2</sub>AgInCl<sub>6</sub> Nanocrystals" @default.
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- W2891026324 doi "https://doi.org/10.1021/jacs.8b07983" @default.
- W2891026324 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6284204" @default.
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