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• W2891032032 abstract "ABSTRACTThe effects of different aggregation–precipitation states of the doping Ba2+-ion on the X-ray-induced generation of F-centres in KCl:Ba2+(675 ppm):Eu2+(27 ppm) single crystals was investigated by optical absorption spectrophotometry. Such states were induced to occur in a controlled manner by subjecting the crystals to suitable thermal treatments. During these treatments, the aggregation–precipitation kinetics of the doping Ba2+-ions was monitored, by optical fluorescence spectrophotometry, utilising the doping Eu2+-ion as an optical probe. As dissolved into the host matrix as forming part of impurity–vacancy (I–V) dipole complexes and small aggregates, divalent barium increases the initial F-colouring rate and F-centre solubility limit by impressive factors of 2 ± 1 and 3 ± 1, respectively, in relation to those of a non-doped crystal. As a constituent of incipient metastable BaCl2-type second-phase precipitates, divalent barium reduces the initial F-colouring rate and F-centre concentration at wh..." @default.
• W2891032032 created "2018-09-27" @default.
• W2891032032 creator A5037699819 @default.
• W2891032032 creator A5068550975 @default.
• W2891032032 date "2018-09-21" @default.
• W2891032032 modified "2023-10-01" @default.
• W2891032032 title "X-ray-induced colouring kinetics of (Ba2+, Eu2+)-doubly doped KCl single crystals: influence of the different aggregation–precipitation states of the doping ions" @default.
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• W2891032032 doi "https://doi.org/10.1080/10420150.2018.1520853" @default.
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