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- W2891043509 abstract "The structure of Fe[x] - Pd[1-x] (0.85>x>0.5) and Fe[x] - Pt[1-x] (0.85>x>0.3) thin film alloys co-deposited from the vapour phase over substrate temperatures (T[s]) ranging over 200-700°C have been examined at room temperature, using X-Ray, Microprobe, TEM and SEM techniques. The sequence of phases developed as T[s] is changed have been explained in terms of three factors: a) The structure of the initial phase, which in turn is a function of the T[o] temperature where DeltaG[bcc-fcc]=0 b) Diffusion at the designated temperature, which depends on both T[s] and the rate of deposition. c) Further transformations which occur on cooling through critical ordering or martensite start temperatures. Based on the co-deposited thin film results, a model is proposed which facilitates the determination of alloy phase diagrams. A direct determination of T[o] temperature in certain composition ranges is also possible through vapour deposition techniques. Preliminary calculation of T[o] confirms the experimental results and the role played by magnetic contributions. The combined experimental data for Fe-Pt alloys confirm the earlier assumption of a eutectoid transformation at about 17at% Pt at around 600°C and provides evidence of the efficacy of thin films for the rapid assessment of low temperature equilibria." @default.
- W2891043509 created "2018-09-27" @default.
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- W2891043509 date "1989-01-01" @default.
- W2891043509 modified "2023-09-22" @default.
- W2891043509 title "The structure of vapour deposited alloys of iron with platinum and palladium" @default.
- W2891043509 hasPublicationYear "1989" @default.
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