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- W2891077258 abstract "Electrocatalysts are readily poisoned during the catalysis of the oxygen reduction reaction (ORR); even air containing traces of SOx and/or NOx significantly decrease the activity and the durability of H2 -O2 fuel cells. Now, a metal-free strategy is reported to develop an efficient anti-poisoning ORR catalyst, which involves the pyrolysis of PDAP-phytic acid super-molecular aggregate (PPSA). The pyrolyzed co-doped carbon acting as a metal-free electrocatalyst shows an enhanced activity for ORR in acidic medium, even under poisoning conditions (SOx , NOx , and POx ). Moreover, P-doping also changes the ORR pathway by yielding less than 4 % of H2 O2 , indicating a four-electron pathway whereas more than>20 % of H2 O2 was recorded for N-doped carbon synthesized from PDAP." @default.
- W2891077258 created "2018-09-27" @default.
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- W2891077258 date "2018-11-12" @default.
- W2891077258 modified "2023-10-15" @default.
- W2891077258 title "An Efficient Anti‐poisoning Catalyst against SO <sub> <i>x</i> </sub> , NO <sub> <i>x</i> </sub> , and PO <sub> <i>x</i> </sub> : P, N‐Doped Carbon for Oxygen Reduction in Acidic Media" @default.
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- W2891077258 doi "https://doi.org/10.1002/anie.201808383" @default.
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