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• W2891082883 abstract "A series of amine-substituted diazocines were synthesized in three steps from methyl 2-aminobenzoate or methyl 3-aminonaphtholate. The saddle-shaped diazocine compounds showed similar interplane angle of 75° despite the different steric bulk of the amine substituents. In electrochemical experiments, these diazocines showed irreversible reduction most likely producing indolo[3,2-b]indoles rather than forming the 10-electron planar aromatic species. The carbazole-substituted naphthodiazocines showed the most interesting photophysical properties with evidence of transition from the saddle-shaped ground state to a planar excited state geometry." @default.
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• W2891082883 date "2018-11-01" @default.
• W2891082883 modified "2023-09-23" @default.
• W2891082883 title "Amine‐Substituted Diazocine Derivatives – Synthesis, Structure, and Photophysical Properties" @default.
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• W2891082883 doi "https://doi.org/10.1002/hlca.201800146" @default.
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