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- W2891152961 abstract "Abstract Dual-state emission (DSE) molecules bridge the gap between aggregation-caused quenching (ACQ) and aggregation-induced emission (AIE), allowing detailed exploration of the mechanisms of molecular luminescence and facilitating practical application of luminescent molecules. In this study, imidazolo[5,4-b]thieno[3,2-e]pyridine DSE molecules were designed by a strategy in which the excited-state intramolecular proton transfer (ESIPT) was enhanced to restrict the twisted intramolecular charge-transfer (TICT) of nonradiative de-excitation processes and the self-assembly is finely controlled. ITP3 and ITP4, as typical examples, are all-powerful DSE molecules with fluorescence quantum yields of 41–83% and 53–92%, respectively. Additionally, their good thermal stability (Tm > 200 °C, T05 > 300 °C) renders them promising candidates for optoelectronic and biological applications." @default.
- W2891152961 created "2018-09-27" @default.
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- W2891152961 date "2019-01-01" @default.
- W2891152961 modified "2023-10-12" @default.
- W2891152961 title "Enhancement of the excited-state intramolecular proton transfer process to produce all-powerful DSE molecules for bridging the gap between ACQ and AIE" @default.
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- W2891152961 doi "https://doi.org/10.1016/j.dyepig.2018.08.066" @default.
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