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- W2891160174 endingPage "6964" @default.
- W2891160174 startingPage "6956" @default.
- W2891160174 abstract "A series of heterometallic Zr3Pd3-trigonal bipyramidal compounds (1–4) was synthesized by two-component coordination-driven self-assembly of cis-protected palladium(II) 90° acceptors with trinuclear carboxylate-bridged zirconocene-based tripodal metallo-ligands. To avoid multiple product formation using two different metal acceptors, we chose trinuclear Zr(IV) metallo-ligands as donors. All the compounds were characterized by NMR and single crystal X-ray diffraction. Among the compounds, the water-soluble compound 2 is capable to encapsulate aromatic guests such as naphthalene and 2-naphthaldehyde. The encapsulation of the guests was confirmed by NMR and UV–vis spectrometry. The binding constants as well as corresponding Gibbs free energy changes were calculated separately from the 1H NMR titration of compound 2 with guests (naphthalene/2-naphthaldehyde)." @default.
- W2891160174 created "2018-09-27" @default.
- W2891160174 creator A5028434389 @default.
- W2891160174 creator A5083410488 @default.
- W2891160174 creator A5087522016 @default.
- W2891160174 date "2018-09-11" @default.
- W2891160174 modified "2023-10-16" @default.
- W2891160174 title "Coordination-Driven Self-assembly of Cyclopentadienyl-Capped Heterometallic Zr–Pd Cages" @default.
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- W2891160174 doi "https://doi.org/10.1021/acs.cgd.8b01147" @default.
- W2891160174 hasPublicationYear "2018" @default.
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