Matches in SemOpenAlex for { <https://semopenalex.org/work/W2891225567> ?p ?o ?g. }
- W2891225567 endingPage "35144" @default.
- W2891225567 startingPage "35137" @default.
- W2891225567 abstract "Theoretically, Cu2O delivers a poor Li storage capacity ∼373.9 mA h g-1 based on a so-called conversion reaction (Cu2O + 2Li → 2Cu + Li2O). Herein, we broke through the bottleneck and acquired an impressive lithium storage capability (1122 mA h g-1) tripled more than the theoretical one by an in situ surface/interface engineering process for the first time. The surface/interface modification enabled us to fabricate ultrasmall nanocrystals of Cu2O with Cu vacancies (VCu) of high concentration, somewhat like monovalent anion doping. Except for the conversion reaction-type capacity, VCu enhancing intercalation pesudocapacitance in Cu2O and its reduction product-Cu also contributed a lot to the Li-storage capability. First-principles calculation substantiated that intercalation energy of Li was severely lowered for both Cu vacancy-rich Cu2O and Cu comparing with their stoichiometric counterparts. Another important factor for the enhancement was the surface/interface organic species themselves which could reversibly store Li by redox reactions. The surface/interface modification for vacancies, vacancy inheritance from metal oxide to single metal, and vacancy-enhancing Li-storage capability in metal oxide and single metal all will inspire us a lot in fabricating new-generation advanced electrodes for rechargeable batteries." @default.
- W2891225567 created "2018-09-27" @default.
- W2891225567 creator A5007650185 @default.
- W2891225567 creator A5015984879 @default.
- W2891225567 creator A5016680184 @default.
- W2891225567 creator A5022837969 @default.
- W2891225567 creator A5058986413 @default.
- W2891225567 creator A5072698669 @default.
- W2891225567 creator A5075575199 @default.
- W2891225567 date "2018-09-20" @default.
- W2891225567 modified "2023-10-15" @default.
- W2891225567 title "Surfaces/Interfaces Modification for Vacancies Enhancing Lithium Storage Capability of Cu<sub>2</sub>O Ultrasmall Nanocrystals" @default.
- W2891225567 cites W1626854854 @default.
- W2891225567 cites W1729427239 @default.
- W2891225567 cites W1969044063 @default.
- W2891225567 cites W1973408623 @default.
- W2891225567 cites W1973553421 @default.
- W2891225567 cites W1977231417 @default.
- W2891225567 cites W1979325119 @default.
- W2891225567 cites W1985410558 @default.
- W2891225567 cites W1988989968 @default.
- W2891225567 cites W2003489030 @default.
- W2891225567 cites W2004432407 @default.
- W2891225567 cites W2007863770 @default.
- W2891225567 cites W2011254969 @default.
- W2891225567 cites W2011836073 @default.
- W2891225567 cites W2017299264 @default.
- W2891225567 cites W2050543622 @default.
- W2891225567 cites W2051849085 @default.
- W2891225567 cites W2064325453 @default.
- W2891225567 cites W2074019461 @default.
- W2891225567 cites W2124461603 @default.
- W2891225567 cites W2134597825 @default.
- W2891225567 cites W2137696182 @default.
- W2891225567 cites W2164104183 @default.
- W2891225567 cites W2215701641 @default.
- W2891225567 cites W2321299915 @default.
- W2891225567 cites W2321515837 @default.
- W2891225567 cites W2371893820 @default.
- W2891225567 cites W2396641716 @default.
- W2891225567 cites W2404711663 @default.
- W2891225567 cites W2517838459 @default.
- W2891225567 cites W2559817462 @default.
- W2891225567 cites W2566581454 @default.
- W2891225567 cites W2588790016 @default.
- W2891225567 cites W2604380954 @default.
- W2891225567 cites W2754928350 @default.
- W2891225567 cites W2784190437 @default.
- W2891225567 cites W2796032804 @default.
- W2891225567 cites W3204206721 @default.
- W2891225567 doi "https://doi.org/10.1021/acsami.8b11592" @default.
- W2891225567 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30234297" @default.
- W2891225567 hasPublicationYear "2018" @default.
- W2891225567 type Work @default.
- W2891225567 sameAs 2891225567 @default.
- W2891225567 citedByCount "29" @default.
- W2891225567 countsByYear W28912255672019 @default.
- W2891225567 countsByYear W28912255672020 @default.
- W2891225567 countsByYear W28912255672021 @default.
- W2891225567 countsByYear W28912255672022 @default.
- W2891225567 countsByYear W28912255672023 @default.
- W2891225567 crossrefType "journal-article" @default.
- W2891225567 hasAuthorship W2891225567A5007650185 @default.
- W2891225567 hasAuthorship W2891225567A5015984879 @default.
- W2891225567 hasAuthorship W2891225567A5016680184 @default.
- W2891225567 hasAuthorship W2891225567A5022837969 @default.
- W2891225567 hasAuthorship W2891225567A5058986413 @default.
- W2891225567 hasAuthorship W2891225567A5072698669 @default.
- W2891225567 hasAuthorship W2891225567A5075575199 @default.
- W2891225567 hasConcept C114221277 @default.
- W2891225567 hasConcept C115537861 @default.
- W2891225567 hasConcept C121332964 @default.
- W2891225567 hasConcept C127413603 @default.
- W2891225567 hasConcept C134018914 @default.
- W2891225567 hasConcept C137824038 @default.
- W2891225567 hasConcept C144082473 @default.
- W2891225567 hasConcept C147789679 @default.
- W2891225567 hasConcept C163258240 @default.
- W2891225567 hasConcept C171250308 @default.
- W2891225567 hasConcept C175854130 @default.
- W2891225567 hasConcept C179104552 @default.
- W2891225567 hasConcept C185592680 @default.
- W2891225567 hasConcept C191897082 @default.
- W2891225567 hasConcept C192562407 @default.
- W2891225567 hasConcept C2778541603 @default.
- W2891225567 hasConcept C2779851234 @default.
- W2891225567 hasConcept C42360764 @default.
- W2891225567 hasConcept C49040817 @default.
- W2891225567 hasConcept C544153396 @default.
- W2891225567 hasConcept C55904794 @default.
- W2891225567 hasConcept C57863236 @default.
- W2891225567 hasConcept C62520636 @default.
- W2891225567 hasConcept C71924100 @default.
- W2891225567 hasConcept C73916439 @default.
- W2891225567 hasConcept C8010536 @default.
- W2891225567 hasConceptScore W2891225567C114221277 @default.
- W2891225567 hasConceptScore W2891225567C115537861 @default.
- W2891225567 hasConceptScore W2891225567C121332964 @default.