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• W2891232390 abstract "A (N,CAr,CAlk) Au(iii) pincer complex has been synthesized from Au(OAc)3 (OAc = OCOCH3) and 2-(3,5-di-tert-butylphenyl)pyridine (L1) involving a Csp3-H bond activation by electrophilic substitution. In agreement with DFT calculations, the resulting complex significantly improves the performance of Au(tpy)(OAcF)2 (tpy = 2-(p-tolyl)pyridine, OAcF = OCOCF3) in the catalytic trifluoroacetylation of acetylene." @default.
• W2891232390 created "2018-09-27" @default.
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• W2891232390 date "2018-01-01" @default.
• W2891232390 modified "2023-10-17" @default.
• W2891232390 title "Synthesis of a (N,C,C) Au(<scp>iii</scp>) pincer complex <i>via</i> C_sp3–H bond activation: increasing catalyst robustness by rational catalyst design" @default.
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• W2891232390 doi "https://doi.org/10.1039/c8cc05489d" @default.
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