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- W2891235400 abstract "A series of self-assembled monomethoxypoly(ethylene glycol)-b-poly(2-hydroxypropyl methacrylate)/poly(2-hydroxypropyl methacrylate) (mPEG113-PHPMA/PHPMA) blends are prepared by aqueous photoinitiated polymerization-induced self-assembly (photo-PISA) of HPMA at room temperature mediated by a binary mixture of mPEG113-CEPA and CEPA (CEPA = 4-cyano-4-(ethylthiocarbonothioylthio)pentanoic acid). High rates of polymerization are observed in all cases, and quantitative monomer conversions can be achieved within 15 min of 405 nm visible light irradiation. Gel permeation chromatography (GPC) measurement confirms good control is maintained under aqueous photo-PISA conditions at different [mPEG113-CEPA]/[CEPA] ratios. A morphological phase diagram is constructed for the first time by changing the degree of polymerization (DP) of PHPMA and [mPEG113-CEPA]/[CEPA] ratio. The introduction of homopolymer promotes the formation of higher order morphologies and larger spherical micelles. The obtained AB/B assemblies can be used as seeds for preparing ABC/BC assemblies by seeded polymerization of hydrophilic or hydrophobic monomers. This method provides a facile platform for in situ preparation of various AB/B and ABC/BC assemblies in water at room temperature." @default.
- W2891235400 created "2018-09-27" @default.
- W2891235400 creator A5001753313 @default.
- W2891235400 creator A5021391070 @default.
- W2891235400 creator A5030357379 @default.
- W2891235400 creator A5056387797 @default.
- W2891235400 creator A5061306102 @default.
- W2891235400 creator A5066716873 @default.
- W2891235400 creator A5084113038 @default.
- W2891235400 date "2018-09-14" @default.
- W2891235400 modified "2023-09-29" @default.
- W2891235400 title "Room Temperature Synthesis of Self-Assembled AB/B and ABC/BC Blends by Photoinitiated Polymerization-Induced Self-Assembly (Photo-PISA) in Water" @default.
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