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• W2891243892 abstract "This study focused on how the local structures in pure [N(CH3)4]2ZnBr4 crystal are affected by the partial replacement of Zn2+ ions with Cu2+ ions. The structures and phase transition temperatures TC of perovskite-type [N(CH3)4]2Zn1-xCuxBr4 (x = 0, 0.5, 0.7, and 1) mixed crystals were almost unchanged by the partial doping of Cu2+ ions. The environments for the local structures of [N(CH3)4]2Zn1-xCuxBr4 mixed systems were studied according to differences in the chemical shifts of the 1H magic angle spinning (MAS) NMR, 13C cross-polarization (CP)/MAS NMR, and 14N NMR spectra. The 1H and 13C NMR results showed that the local environments of 1H and 13C nuclei near TC are not affected by substituting Zn2+ ions with Cu2+ ions, whereas the 14N NMR results showed that the local environment is affected near TC. Consequently, the main indicators of the phase transition in [N(CH3)4]2Zn1-xCuxBr4 are related to the ferroelastic characteristics with different orientations." @default.
• W2891243892 created "2018-09-27" @default.
• W2891243892 creator A5064959628 @default.
• W2891243892 date "2018-09-20" @default.
• W2891243892 modified "2023-10-17" @default.
• W2891243892 title "Effect on Local Structure and Phase Transition of Perovskite-Type [N(CH3)4]2Zn1-xCuxBr4 (x = 0, 0.5, 0.7, and 1) Crystals with the Various Doping of Cu2+ Ions" @default.
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• W2891243892 doi "https://doi.org/10.1038/s41598-018-32022-z" @default.
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