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• W2891289738 abstract "The TiN/$mathrm{Si}{mathrm{N}}_{x}$ nanocomposite and nanolaminate systems are the archetype for super if not ultrahard materials. Yet, the nature of the $mathrm{Si}{mathrm{N}}_{x}$ tissue phase is debated. Here, we show by atomically resolved electron microscopy methods that $mathrm{Si}{mathrm{N}}_{x}$ is epitaxially stabilized in a NaCl structure on the adjacent TiN(001) surfaces. Additionally, electron energy loss spectroscopy, supported by first-principles density functional theory calculations infer that $mathrm{Si}{mathrm{N}}_{x}$ hosts Si vacancies." @default.
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• W2891289738 date "2018-09-20" @default.
• W2891289738 modified "2023-10-14" @default.
• W2891289738 title "Resolving the debated atomic structure of the metastable cubic SiNx tissue phase in nanocomposites with TiN" @default.
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• W2891289738 doi "https://doi.org/10.1103/physrevmaterials.2.093608" @default.
• W2891289738 hasPublicationYear "2018" @default.
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