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- W2891297931 abstract "Abstract An efficient and regioselective electrophilic bromolactonization of cyclopropylmethyl diesters using triphenylphosphine sulfide (Ph 3 PS) or diphenyl selenide (Ph 2 Se) as the Lewis basic chalcogenide catalyst has been developed. It was observed that Ph 3 PS favored the formation of anti ‐diastereomer and yielded the multi‐functional γ‐lactones. Interestingly, the diastereoselectivity was reversed when using Ph 2 Se as a catalyst where the syn ‐product instead of the anti ‐product was favored. magnified image" @default.
- W2891297931 created "2018-09-27" @default.
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- W2891297931 date "2018-09-26" @default.
- W2891297931 modified "2023-10-17" @default.
- W2891297931 title "Electrophilic Bromolactonization of Cyclopropyl Diesters Using Lewis Basic Chalcogenide Catalysts" @default.
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- W2891297931 doi "https://doi.org/10.1002/adsc.201800886" @default.
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