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- W2891335588 abstract "Developing highly sensitive and specific methods for tracking hypochlorite (ClO−) is highly desirable for unraveling its pathophysiological function in biological systems. Herein, a simple anthracene derivative (probe 1) has been developed as a turn-on fluorescent probe for detecting ClO− in living cells. Probe 1 exhibited excellent specificity for ClO− over other various biologically relevant species. Meanwhile, probe 1 also showed a highly sensitive (145-fold fluorescence enhancement) response toward ClO− with a low detection limit of 3.17 nM. Probe 1 could efficiently sense ClO− with a rapid response time and wide pH range in aqueous solution. The sensing mechanism was confirmed by NMR spectroscopic analysis and ESI-MS analysis. Density functional theory (DFT) calculations were employed for further estimating the optical behaviour of probe 1 before and after the oxidation reaction with ClO−. Moreover, probe 1 was quite suitable for the quantitative detection of ClO− in environmental water samples. Additionally, probe 1 was successfully utilized to label exogenous ClO− in HeLa cells and endogenous ClO− in RAW 264.7 macrophage cells. Therefore, probe 1 could be used as a promising method for monitoring ClO− in biological applications." @default.
- W2891335588 created "2018-09-27" @default.
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- W2891335588 date "2019-02-01" @default.
- W2891335588 modified "2023-10-16" @default.
- W2891335588 title "A highly specific and sensitive turn-on fluorescence probe for hypochlorite detection based on anthracene fluorophore and its bioimaging applications" @default.
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- W2891335588 doi "https://doi.org/10.1016/j.dyepig.2018.09.046" @default.
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