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- W2891339596 abstract "The present work reports a novel strategy of assembling maghemite (γ-Fe2O3) nanoparticles (NPs) in mesoporous silica host for developing a highly efficient MRI contrast probe. Shrinkage of hydrophobic environment due to the continuous evaporation of chloroform from Chloroform-in-Water emulsions pushes the hydrophobic γ-Fe2O3 NPs towards the hydrophobic pores of silica spheres resulting in a water soluble dense assembly structure. Mesoporous silica only with straight pores is found to be suitable for this particular entrapment process, while with curved and twisted pores, NPs are found to be seated on the surface only. So-developed assembly system has retained the superparamagnetic behaviour of its comprising NPs and exhibited high colloidal stability and biocompatibility. A significant enhancement in MRI transverse relaxivity to 386.2 mM−1 s−1 from 191.8 mM−1 s−1 of isolated primary γ-Fe2O3 NPs, has been obtained due to the strong magnetic field generated by the large number of NPs packed in the porous channels and consequent faster relaxation process. The fabrication strategy can be extended for the development of designed secondary nanostructures with new magnetic effects and physical properties." @default.
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- W2891339596 date "2018-10-01" @default.
- W2891339596 modified "2023-09-26" @default.
- W2891339596 title "Zinc oxide nano- and bulk-materials interfere with immunometabolism" @default.
- W2891339596 doi "https://doi.org/10.1016/j.toxlet.2018.06.844" @default.
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