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- W2891366706 abstract "A study on the fundamental properties of Gd 5− x La x Si 1.8 Ge 2.2 pseudo‐binary compounds with x = 1, 2, 3, 4, and 5 is performed by means of X‐ray powder diffraction (XRD) and magnetic measurements. An evolution from a monoclinic (M) Gd 5 Si 2 Ge 2 ‐type to a tetragonal (T) Zr 5 Si 4 ‐type structure, with the addition of La, is observed, finding that the T phase is stable for x ≥ 2. A monotonic expansion of the unit cell volume with a rate of 28 Å 3 /La by increasing the content of the non‐magnetic La ions in the system influences significantly the overall magnetic behavior. For instance, T C decreases in a rate of d T C /d x = −47.8 K La −1 ; and a considerable hysteresis reduction is observed as a result of the change on the nature of the phase transition from a first to a second‐order one. Hence, these results reveal the impact of a non‐magnetic La substitution on both magnetic and crystallographic properties of this series." @default.
- W2891366706 created "2018-09-27" @default.
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- W2891366706 date "2018-09-06" @default.
- W2891366706 modified "2023-09-26" @default.
- W2891366706 title "Lanthanum Dilution Effects on the Giant Magnetocaloric Gd <sub>5</sub> Si <sub>1.8</sub> Ge <sub>2.2</sub> Compound" @default.
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- W2891366706 doi "https://doi.org/10.1002/pssb.201800101" @default.
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