Matches in SemOpenAlex for { <https://semopenalex.org/work/W2891410202> ?p ?o ?g. }
- W2891410202 endingPage "121" @default.
- W2891410202 startingPage "116" @default.
- W2891410202 abstract "There is a general desire to improve the configuration of industrial catalysts by taking advantage of the intrinsic properties of metal oxides. On an inverse oxide/metal catalyst, the reactants can interact with defect sites of the oxide nanoparticles, metal sites, and the metal-oxide interface. In this study, we have investigated the oxidation of carbon monoxide (CO + 0.5O2 → CO2) and the water-gas shift (WGS, CO + H2O → H2 + CO2) reaction on a series of ZnO/Cu(111) surfaces prepared in different ways. Oxidation of a Zn-Cu(111) alloys with O2 at 460 K produces ZnO/CuOx/Cu(111) systems where the size of the ZnO islands is in the range of 5–20 nm. These systems are highly active for the oxidation of CO at moderate temperatures (400–500 K) but have problems of stability when performing the water-gas shift at temperatures above 550 K. ZnO/CuOx/Cu(111) surfaces prepared by vapor deposition of Zn at 600 K in O2 exhibit islands of ZnO which are extremely large (400–500 nm) and contain a minimum of 3–4 layers of the oxide. These large islands of ZnO are not as chemically active as the small ZnO clusters yet they have high stability and produce ZnOCu interfaces which are efficient as catalysts for the water-gas shift reaction at 550–625 K." @default.
- W2891410202 created "2018-09-27" @default.
- W2891410202 creator A5012954207 @default.
- W2891410202 creator A5023375972 @default.
- W2891410202 creator A5031216912 @default.
- W2891410202 creator A5037717754 @default.
- W2891410202 creator A5038550012 @default.
- W2891410202 creator A5039143893 @default.
- W2891410202 creator A5050652219 @default.
- W2891410202 creator A5065398556 @default.
- W2891410202 creator A5076281422 @default.
- W2891410202 creator A5085268445 @default.
- W2891410202 date "2019-03-01" @default.
- W2891410202 modified "2023-10-11" @default.
- W2891410202 title "The behavior of inverse oxide/metal catalysts: CO oxidation and water-gas shift reactions over ZnO/Cu(111) surfaces" @default.
- W2891410202 cites W141843092 @default.
- W2891410202 cites W1966083557 @default.
- W2891410202 cites W1989686935 @default.
- W2891410202 cites W1997234402 @default.
- W2891410202 cites W2002056049 @default.
- W2891410202 cites W2003544253 @default.
- W2891410202 cites W2011575245 @default.
- W2891410202 cites W2020413077 @default.
- W2891410202 cites W2030678365 @default.
- W2891410202 cites W2038689807 @default.
- W2891410202 cites W2044656246 @default.
- W2891410202 cites W2048590151 @default.
- W2891410202 cites W2052727097 @default.
- W2891410202 cites W2078023268 @default.
- W2891410202 cites W2082279765 @default.
- W2891410202 cites W2092714503 @default.
- W2891410202 cites W2120225666 @default.
- W2891410202 cites W2148587445 @default.
- W2891410202 cites W2152193384 @default.
- W2891410202 cites W2470246762 @default.
- W2891410202 cites W2600566292 @default.
- W2891410202 cites W2747629573 @default.
- W2891410202 cites W2749136943 @default.
- W2891410202 cites W2789254090 @default.
- W2891410202 cites W2804678790 @default.
- W2891410202 cites W2834160584 @default.
- W2891410202 cites W4249261575 @default.
- W2891410202 doi "https://doi.org/10.1016/j.susc.2018.09.008" @default.
- W2891410202 hasPublicationYear "2019" @default.
- W2891410202 type Work @default.
- W2891410202 sameAs 2891410202 @default.
- W2891410202 citedByCount "27" @default.
- W2891410202 countsByYear W28914102022018 @default.
- W2891410202 countsByYear W28914102022019 @default.
- W2891410202 countsByYear W28914102022020 @default.
- W2891410202 countsByYear W28914102022021 @default.
- W2891410202 countsByYear W28914102022022 @default.
- W2891410202 countsByYear W28914102022023 @default.
- W2891410202 crossrefType "journal-article" @default.
- W2891410202 hasAuthorship W2891410202A5012954207 @default.
- W2891410202 hasAuthorship W2891410202A5023375972 @default.
- W2891410202 hasAuthorship W2891410202A5031216912 @default.
- W2891410202 hasAuthorship W2891410202A5037717754 @default.
- W2891410202 hasAuthorship W2891410202A5038550012 @default.
- W2891410202 hasAuthorship W2891410202A5039143893 @default.
- W2891410202 hasAuthorship W2891410202A5050652219 @default.
- W2891410202 hasAuthorship W2891410202A5065398556 @default.
- W2891410202 hasAuthorship W2891410202A5076281422 @default.
- W2891410202 hasAuthorship W2891410202A5085268445 @default.
- W2891410202 hasBestOaLocation W28914102021 @default.
- W2891410202 hasConcept C106773901 @default.
- W2891410202 hasConcept C127413603 @default.
- W2891410202 hasConcept C147534773 @default.
- W2891410202 hasConcept C161790260 @default.
- W2891410202 hasConcept C171250308 @default.
- W2891410202 hasConcept C178790620 @default.
- W2891410202 hasConcept C179104552 @default.
- W2891410202 hasConcept C185592680 @default.
- W2891410202 hasConcept C191897082 @default.
- W2891410202 hasConcept C192562407 @default.
- W2891410202 hasConcept C194439259 @default.
- W2891410202 hasConcept C204242273 @default.
- W2891410202 hasConcept C2779851234 @default.
- W2891410202 hasConcept C42360764 @default.
- W2891410202 hasConcept C512735826 @default.
- W2891410202 hasConcept C544153396 @default.
- W2891410202 hasConcept C55493867 @default.
- W2891410202 hasConcept C57410435 @default.
- W2891410202 hasConcept C66114498 @default.
- W2891410202 hasConceptScore W2891410202C106773901 @default.
- W2891410202 hasConceptScore W2891410202C127413603 @default.
- W2891410202 hasConceptScore W2891410202C147534773 @default.
- W2891410202 hasConceptScore W2891410202C161790260 @default.
- W2891410202 hasConceptScore W2891410202C171250308 @default.
- W2891410202 hasConceptScore W2891410202C178790620 @default.
- W2891410202 hasConceptScore W2891410202C179104552 @default.
- W2891410202 hasConceptScore W2891410202C185592680 @default.
- W2891410202 hasConceptScore W2891410202C191897082 @default.
- W2891410202 hasConceptScore W2891410202C192562407 @default.
- W2891410202 hasConceptScore W2891410202C194439259 @default.
- W2891410202 hasConceptScore W2891410202C204242273 @default.
- W2891410202 hasConceptScore W2891410202C2779851234 @default.
- W2891410202 hasConceptScore W2891410202C42360764 @default.