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- W2891415204 abstract "Herein, using first-principles calculations we predict magnetization reorientation and large perpendicular magnetic anisotropy (PMA) in spinel ${mathrm{Fe}}_{3}{mathrm{O}}_{4}$/MgO heterostructure by replacing the octahedral Fe ions with Cu. The substitutional ${mathrm{Cu}}^{2+}$ ions prefer the octahedral site within the xy-plane layer in an inverse spinel structure, which is associated with the Jahn-Teller tetragonal and $xy$-plane twisted distortions. While magnetization of ${mathrm{Fe}}_{3}{mathrm{O}}_{4}$/MgO is significantly reduced in ${mathrm{CuFe}}_{2}{mathrm{O}}_{4}$/MgO, the presence of the substitutional ${mathrm{Cu}}^{2+}$ ions reorients magnetization from an in-plane to perpendicular magnetic anisotropy. More remarkably, PMA further increases gradually with the film thickness of ${mathrm{CuFe}}_{2}{mathrm{O}}_{4}$ layers in the ${mathrm{CuFe}}_{2}{mathrm{O}}_{4}$/MgO heterostructure. The underlying mechanism for this large PMA is the interplay of the spin-orbit-coupled Cu ${d}_{xy}--{d}_{{x}^{2}ensuremath{-}{y}^{2}}$ states in the center layers and the Fe ${d}_{{z}^{2}}$--O ${p}_{z}$ hybridization at the interface. These findings point toward the feasibility of reducing magnetization and enhancing PMA in spinel structures for spintronics applications." @default.
- W2891415204 created "2018-09-27" @default.
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- W2891415204 date "2018-09-10" @default.
- W2891415204 modified "2023-10-12" @default.
- W2891415204 title "First-principles study of magnetization reorientation and large perpendicular magnetic anisotropy in <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mi>Cu</mml:mi><mml:mrow><mml:msub><mml:mi>Fe</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi mathvariant=normal>O</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:mrow><mml:mo>/</mml:mo><mml:mi>MgO</mml:mi></mml:math> heterostructures" @default.
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- W2891415204 doi "https://doi.org/10.1103/physrevb.98.094408" @default.
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