Matches in SemOpenAlex for { <https://semopenalex.org/work/W2891447401> ?p ?o ?g. }
- W2891447401 endingPage "2111" @default.
- W2891447401 startingPage "2103" @default.
- W2891447401 abstract "Abstract The design of microporous hybrid materials, tailored for diverse applications, is a key to address our modern society's imperative of sustainable technologies. Prerequisites are flexible customization of host–guest interactions by incorporating various types of functionality and by adjusting the pore structure. On that score, metal–organic frameworks (MOFs) have been the reference in the past decades. More recently, a new class of microporous hybrid materials emerged, microporous organically pillared layered silicates (MOPS). MOPS are synthesized by simple ion exchange of organic or metal complex cations in synthetic layered silicates. MOFs and MOPSs share the features of “component modularity” and “functional porosity”. While both, MOFs and MOPS maintain the intrinsic characteristics of their building blocks, new distinctive properties arise from their assemblage. MOPS are unique since allowing for simultaneous and continuous tuning of micropores in the sub‐Ångström range. Consequently, with MOPS the adsorbent recognition may be optimized without the need to explore different framework topologies. Similar to the third generation of MOFs (also termed soft porous crystals), MOPS are structurally ordered, permanently microporous solids that may also show a reversible structural flexibility above a distinct threshold pressure of certain adsorbents. This structural dynamism of MOPS can be utilized by meticulously adjusting the charge density of the silicate layers to the polarizability of the adsorbent leading to different gate opening mechanisms. The potential of MOPS is far from being fully explored. This Concept article highlights the main features of MOPS and illustrates promising directions for further research." @default.
- W2891447401 created "2018-09-27" @default.
- W2891447401 creator A5026002243 @default.
- W2891447401 creator A5032535843 @default.
- W2891447401 creator A5056637892 @default.
- W2891447401 creator A5069743496 @default.
- W2891447401 date "2018-11-29" @default.
- W2891447401 modified "2023-10-16" @default.
- W2891447401 title "Microporous Organically Pillared Layered Silicates (MOPS): A Versatile Class of Functional Porous Materials" @default.
- W2891447401 cites W140172893 @default.
- W2891447401 cites W1505562661 @default.
- W2891447401 cites W1570491439 @default.
- W2891447401 cites W1767102537 @default.
- W2891447401 cites W1876006411 @default.
- W2891447401 cites W1947786635 @default.
- W2891447401 cites W1950726183 @default.
- W2891447401 cites W1963858241 @default.
- W2891447401 cites W1967401337 @default.
- W2891447401 cites W1969555886 @default.
- W2891447401 cites W1992197068 @default.
- W2891447401 cites W1994052174 @default.
- W2891447401 cites W1999937609 @default.
- W2891447401 cites W2010052854 @default.
- W2891447401 cites W2012178448 @default.
- W2891447401 cites W2014128072 @default.
- W2891447401 cites W2015194523 @default.
- W2891447401 cites W2019903682 @default.
- W2891447401 cites W2021767761 @default.
- W2891447401 cites W2022167379 @default.
- W2891447401 cites W2025336678 @default.
- W2891447401 cites W2032679201 @default.
- W2891447401 cites W2040916133 @default.
- W2891447401 cites W2040995650 @default.
- W2891447401 cites W2042559221 @default.
- W2891447401 cites W2052385321 @default.
- W2891447401 cites W2056040282 @default.
- W2891447401 cites W2061132599 @default.
- W2891447401 cites W2061957955 @default.
- W2891447401 cites W2062904068 @default.
- W2891447401 cites W2066784839 @default.
- W2891447401 cites W2066991705 @default.
- W2891447401 cites W2076662543 @default.
- W2891447401 cites W2077099196 @default.
- W2891447401 cites W2081408517 @default.
- W2891447401 cites W2086670878 @default.
- W2891447401 cites W2091161882 @default.
- W2891447401 cites W2099486431 @default.
- W2891447401 cites W2100640861 @default.
- W2891447401 cites W2103829561 @default.
- W2891447401 cites W2105631122 @default.
- W2891447401 cites W2108712263 @default.
- W2891447401 cites W2115764422 @default.
- W2891447401 cites W2115958483 @default.
- W2891447401 cites W2118911588 @default.
- W2891447401 cites W2119640781 @default.
- W2891447401 cites W2123736674 @default.
- W2891447401 cites W2128141951 @default.
- W2891447401 cites W2128405848 @default.
- W2891447401 cites W2130831264 @default.
- W2891447401 cites W2140462678 @default.
- W2891447401 cites W2141786379 @default.
- W2891447401 cites W2144790873 @default.
- W2891447401 cites W2147717613 @default.
- W2891447401 cites W2148233016 @default.
- W2891447401 cites W2150660847 @default.
- W2891447401 cites W2151985601 @default.
- W2891447401 cites W2162846314 @default.
- W2891447401 cites W2163242195 @default.
- W2891447401 cites W2206425472 @default.
- W2891447401 cites W2274294414 @default.
- W2891447401 cites W2288897667 @default.
- W2891447401 cites W2297298019 @default.
- W2891447401 cites W2319066054 @default.
- W2891447401 cites W2322505461 @default.
- W2891447401 cites W2325265950 @default.
- W2891447401 cites W2327096520 @default.
- W2891447401 cites W2327294914 @default.
- W2891447401 cites W2331078365 @default.
- W2891447401 cites W2331408225 @default.
- W2891447401 cites W2333890779 @default.
- W2891447401 cites W2335579250 @default.
- W2891447401 cites W2336169672 @default.
- W2891447401 cites W2339540635 @default.
- W2891447401 cites W2343085234 @default.
- W2891447401 cites W2402426102 @default.
- W2891447401 cites W2413048531 @default.
- W2891447401 cites W2485720165 @default.
- W2891447401 cites W2561735165 @default.
- W2891447401 cites W2563212877 @default.
- W2891447401 cites W2565156111 @default.
- W2891447401 cites W2566685601 @default.
- W2891447401 cites W2567945411 @default.
- W2891447401 cites W2572017947 @default.
- W2891447401 cites W2603251000 @default.
- W2891447401 cites W2605043693 @default.
- W2891447401 cites W2617135749 @default.
- W2891447401 cites W2752657538 @default.
- W2891447401 cites W2766801193 @default.