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- W2891453232 endingPage "12322" @default.
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- W2891453232 abstract "An intermolecular anti-Markovnikov hydroamination of alkenes has been developed using triethyl phosphite and N-hydroxyphthalimide. The process tolerates a wide range of alkenes, including vinyl ethers, silanes, and sulfides as well as electronically unbiased terminal and internal alkenes. The resultant N-alkylphthalimides can readily be transformed to the corresponding primary amines. Mechanistic probes indicate that the process is mediated via a phosphite promoted radical deoxygenation of N-hydroxyphthalimide to access phthalimidyl radicals." @default.
- W2891453232 created "2018-09-27" @default.
- W2891453232 creator A5006323272 @default.
- W2891453232 creator A5029024835 @default.
- W2891453232 date "2018-09-07" @default.
- W2891453232 modified "2023-10-06" @default.
- W2891453232 title "Intermolecular Radical Mediated Anti-Markovnikov Alkene Hydroamination Using <i>N</i>-Hydroxyphthalimide" @default.
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- W2891453232 doi "https://doi.org/10.1021/jacs.8b06881" @default.
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