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• W2891473496 abstract "Hexaferrites are an important class of magnetic oxides with applications in data storage and electronics. Their crystal structures are highly modular, consisting of Fe- or Ba-rich close-packed blocks that can be stacked in different sequences to form a multitude of unique structures, producing large anisotropic unit cells with lattice parameters typically >100 Å along the stacking axis. This has limited atomic-resolution structure solutions to relatively simple examples such as Ba 2 Zn 2 Fe 12 O 22 , whilst longer stacking sequences have been modelled only in terms of block sequences, with no refinement of individual atomic coordinates or occupancies. This paper describes the growth of a series of complex hexaferrite crystals, their atomic-level structure solution by high-resolution synchrotron X-ray diffraction, electron diffraction and imaging methods, and their physical characterization by magnetometry. The structures include a new hexaferrite stacking sequence, with the longest lattice parameter of any hexaferrite with a fully determined structure." @default.
• W2891473496 created "2018-09-27" @default.
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• W2891473496 date "2018-09-12" @default.
• W2891473496 modified "2023-10-18" @default.
• W2891473496 title "Structure determination and crystal chemistry of large repeat mixed-layer hexaferrites" @default.
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• W2891473496 doi "https://doi.org/10.1107/s2052252518011351" @default.
• W2891473496 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6211530" @default.
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