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• W2891485668 abstract "Herein, a nanoporous silver surface treated with gadolinia-doped ceria (GDC) is evaluated as a cathode for intermediate-temperature solid oxide fuel cells operating below 500 °C. For uniform surface treatment on the porous silver, aerosol-assisted chemical vapor deposition (AACVD) is used; it is a non-vacuum process and is considered as an economical alternative to the expensive vacuum-environment thin-film fabrication methods. Consequently, a uniform coating of AACVD GDC on the Ag surface is successfully achieved, which is confirmed by high-resolution transmission electron microscopy. The optimized amount of AACVD GDC enhances fuel cell performance compared to cells with bare Ag, in terms of the power and long-term stability measured by current–voltage characteristics, electrochemical impedance spectroscopy, and potentiostatic amperometry. This performance is even more significant than that from the cell with a platinum cathode, which, to our best knowledge, is known as the best-performing catalyst for solid oxide fuel cells in the intermediate- and low-temperature regimes. The power enhancement is attributed to the improved kinetics with the GDC surface coating; moreover, this oxide decoration is proven effective in preventing the thermal agglomeration of Ag, as confirmed by the morphology comparison before and after the long-term test." @default.
• W2891485668 created "2018-09-27" @default.
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• W2891485668 date "2018-10-01" @default.
• W2891485668 modified "2023-09-27" @default.
• W2891485668 title "Nanoporous silver cathode surface-treated by aerosol-assisted chemical vapor deposition of gadolinia-doped ceria for intermediate-temperature solid oxide fuel cells" @default.
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• W2891485668 doi "https://doi.org/10.1016/j.jpowsour.2018.09.031" @default.
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