FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2891492088> ?p ?o ?g. }

• W2891492088 endingPage "12552" @default.
• W2891492088 startingPage "12545" @default.
• W2891492088 abstract "Hydrolytically stable adsorbents are needed for water vapor sorption related applications; however, design principles for porous materials with tunable water sorption behavior are not yet established. Here, we report that a platform of fourth-generation metal–organic materials (MOMs) with rigid frameworks and self-switching pores can adapt their pores to modulate water sorption. This platform is based upon the hydrolytically stable material CMOM-3S, which exhibits bnn topology and is composed of rod building blocks based upon S-mandelate ligands, 4,4-bipyridine ligands, and extraframework triflate anions. Isostructural variants of CMOM-3S were prepared using substituted R-mandelate ligands and exhibit diverse water vapor uptakes (20–67 cm3/g) and pore filling pressures (P/P0, 0.55–0.75). [Co2(R-4-Cl-man)2(bpy)3](OTf) (33R) is of particular interest because of its unusual isotherm. Insight into the different water sorption properties of the materials studied was gained from analysis of in situ vibrational spectra, which indicate self-switching pores via perturbation of extraframework triflate anions and mandelate linker ligands to generate distinctive water binding sites. Water vapor adsorption was studied using in situ differential spectra that reveal gradual singlet water occupancy followed by aggregation of water clusters in the channels upon increasing pressure. First-principles calculations identified the water binding sites and provide structural insight on how adsorbed water molecules affect the structures and the binding sites. Stronger triflate hydrogen bonding to the framework along with significant charge redistribution were determined for water binding in 33R. This study provides insight into a new class of fourth-generation (self-switching pores) MOM and the resulting effect upon water vapor sorption properties." @default.
• W2891492088 created "2018-09-27" @default.
• W2891492088 creator A5000199680 @default.
• W2891492088 creator A5001382768 @default.
• W2891492088 creator A5011486136 @default.
• W2891492088 creator A5022511116 @default.
• W2891492088 creator A5044900607 @default.
• W2891492088 creator A5045372922 @default.
• W2891492088 creator A5051239060 @default.
• W2891492088 creator A5072270795 @default.
• W2891492088 creator A5079853183 @default.
• W2891492088 date "2018-09-08" @default.
• W2891492088 modified "2023-10-18" @default.
• W2891492088 title "Modulation of Water Vapor Sorption by a Fourth-Generation Metal–Organic Material with a Rigid Framework and Self-Switching Pores" @default.
• W2891492088 cites W1611493559 @default.
• W2891492088 cites W1970820491 @default.
• W2891492088 cites W1973624041 @default.
• W2891492088 cites W1974921864 @default.
• W2891492088 cites W1977132874 @default.
• W2891492088 cites W1979544533 @default.
• W2891492088 cites W1982731022 @default.
• W2891492088 cites W1985082738 @default.
• W2891492088 cites W1985592927 @default.
• W2891492088 cites W1986022082 @default.
• W2891492088 cites W1986616529 @default.
• W2891492088 cites W1989118706 @default.
• W2891492088 cites W1995004090 @default.
• W2891492088 cites W1995541511 @default.
• W2891492088 cites W1999717844 @default.
• W2891492088 cites W1999937609 @default.
• W2891492088 cites W2006591011 @default.
• W2891492088 cites W2007082361 @default.
• W2891492088 cites W2014128072 @default.
• W2891492088 cites W2021523927 @default.
• W2891492088 cites W2021767761 @default.
• W2891492088 cites W2022085591 @default.
• W2891492088 cites W2026528874 @default.
• W2891492088 cites W2043535587 @default.
• W2891492088 cites W2050863372 @default.
• W2891492088 cites W2062269633 @default.
• W2891492088 cites W2062904068 @default.
• W2891492088 cites W2078399627 @default.
• W2891492088 cites W2083222334 @default.
• W2891492088 cites W2084198473 @default.
• W2891492088 cites W2088221221 @default.
• W2891492088 cites W2092454962 @default.
• W2891492088 cites W2093182007 @default.
• W2891492088 cites W2095189801 @default.
• W2891492088 cites W2096696005 @default.
• W2891492088 cites W2098336232 @default.
• W2891492088 cites W2103829561 @default.
• W2891492088 cites W2105631122 @default.
• W2891492088 cites W2147032026 @default.
• W2891492088 cites W2148069817 @default.
• W2891492088 cites W2163242195 @default.
• W2891492088 cites W2166689829 @default.
• W2891492088 cites W2229321625 @default.
• W2891492088 cites W2239728965 @default.
• W2891492088 cites W2271095341 @default.
• W2891492088 cites W2279533943 @default.
• W2891492088 cites W2283564633 @default.
• W2891492088 cites W2313181959 @default.
• W2891492088 cites W2317091803 @default.
• W2891492088 cites W2318952028 @default.
• W2891492088 cites W2325161613 @default.
• W2891492088 cites W2325374631 @default.
• W2891492088 cites W2331491299 @default.
• W2891492088 cites W2331550880 @default.
• W2891492088 cites W2332410494 @default.
• W2891492088 cites W2335615475 @default.
• W2891492088 cites W2463436373 @default.
• W2891492088 cites W2558046062 @default.
• W2891492088 cites W2561762587 @default.
• W2891492088 cites W2566268553 @default.
• W2891492088 cites W2581591217 @default.
• W2891492088 cites W2588812077 @default.
• W2891492088 cites W2606549030 @default.
• W2891492088 cites W2732727805 @default.
• W2891492088 cites W2735797865 @default.
• W2891492088 cites W2741818978 @default.
• W2891492088 cites W2789787155 @default.
• W2891492088 cites W3099461197 @default.
• W2891492088 cites W3103637439 @default.
• W2891492088 cites W600932620 @default.
• W2891492088 doi "https://doi.org/10.1021/jacs.8b07290" @default.
• W2891492088 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30196697" @default.
• W2891492088 hasPublicationYear "2018" @default.
• W2891492088 type Work @default.
• W2891492088 sameAs 2891492088 @default.
• W2891492088 citedByCount "39" @default.
• W2891492088 countsByYear W28914920882019 @default.
• W2891492088 countsByYear W28914920882020 @default.
• W2891492088 countsByYear W28914920882021 @default.
• W2891492088 countsByYear W28914920882022 @default.
• W2891492088 countsByYear W28914920882023 @default.
• W2891492088 crossrefType "journal-article" @default.
• W2891492088 hasAuthorship W2891492088A5000199680 @default.
• W2891492088 hasAuthorship W2891492088A5001382768 @default.

• next