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• W2891493435 abstract "Scheelite-type non-stoichiometric Ba1+x WO4 (0 ≤ x ≤ 0.04) ceramics were synthesized by a conventional solid-state reaction method. X-ray diffraction patterns showed that the main phase is a tetragonal scheelite structure with space group I41/a. The vibrational modes were obtained from Raman spectra, which were assigned and illustrated. The intrinsic properties were obtained by Clausius-Mosotti equation (C–M) and the damping equation, and there is a positive relationship between the FWHM values of the Bg(Ba) modes and the dielectric losses (calculated by the damping equation), as well as a negative correlation between the Raman shifts of the Eg (near 355 cm−1) and the dielectric constants (deduced by C–M equation). The far-infrared reflectivity spectra were analyzed by the four-parameter semi-quantum (FPSQ) model to calculate the intrinsic properties of the samples, which agreed well with those values obtained by the measured data." @default.
• W2891493435 created "2018-09-27" @default.
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• W2891493435 date "2018-09-14" @default.
• W2891493435 modified "2023-09-26" @default.
• W2891493435 title "Phonon characteristics, crystal structures and intrinsic properties of non-stoichiometric Ba_1+xWO₄ ceramics" @default.
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• W2891493435 doi "https://doi.org/10.1088/2053-1591/aadf5e" @default.
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