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• W2891494590 abstract "Abstract Eu3+-doped strontium phosphorous silicate phosphors were synthesized at 200 °C using microwave-assisted reaction and their crystal structure and optical properties were investigated. Cation/anion ratio and SiO4 content in strontium phosphorous silicate are sensitive to processing conditions such as pH and starting composition of reaction precursors. Stoichiometric Sr5(PO4)2(SiO4):Eu3+ phosphor prepared by the microwave reaction emits more intense red light than previously reported Sr5(PO4)2(SiO4):Eu3+ and Sr5(PO4)3OH:Eu3+ phosphors. As the amount of SiO4 in the anion site increases and P/Si ratio gets close to stoichiometry, the intensity of red luminescence with a narrow band width increases. Strong red luminescence from Sr5(PO4)2(SiO4):Eu3+ synthesized by the microwave-reaction is explained from the viewpoint of defect formation, charge compensation during co-doping process, and local structural symmetry. Large electric dipoles near Eu3+ ions enhance photoluminescence of Sr5(PO4)2(SiO4):Eu3+ from 5D0-7F2 transition at a peak wavelength of 614 nm. This study shows that Sr5(PO4)2(SiO4):Eu3+ prepared by the microwave reaction is promising red phosphor for white light emitting diode." @default.
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• W2891494590 date "2019-01-01" @default.
• W2891494590 modified "2023-10-16" @default.
• W2891494590 title "Luminescence and electric dipole in Eu3+ doped strontium phosphate: Effect of SiO4" @default.
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• W2891494590 doi "https://doi.org/10.1016/j.jallcom.2018.09.151" @default.
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