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- W2891516864 abstract "Conductive metal–organic frameworks (c-MOFs) have shown outstanding performance in energy storage and electrocatalysis. Varying the bridging metal species and the coordinating atom are versatile approaches to tune their intrinsic electronic properties in c-MOFs. Herein we report the first synthesis of the oxygen analog of M3(C6X6)2 (X = NH, S) family using Cu(II) and hexahydroxybenzene (HHB), namely Cu-HHB [Cu3(C6O6)2], through a kinetically controlled approach with a competing coordination reagent. We also successfully demonstrate an economical synthetic approach using tetrahydroxyquinone as the starting material. Cu-HHB was found to have a partially eclipsed packing between adjacent 2D layers and a bandgap of approximately 1 eV. The addition of Cu-HHB to the family of synthetically realized M3(C6X6)2 c-MOFs will enable greater understanding of the influence of the organic linkers and metals, and further broadens the range of applications for these materials." @default.
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- W2891516864 date "2018-09-03" @default.
- W2891516864 modified "2023-10-17" @default.
- W2891516864 title "Synthetic Routes for a 2D Semiconductive Copper Hexahydroxybenzene Metal–Organic Framework" @default.
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- W2891516864 doi "https://doi.org/10.1021/jacs.8b06666" @default.
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