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- W2891530813 abstract "In the present work, trivalent europium (Eu3+) ion activated Na2Y2B2O7 red phosphors have been synthesized through high-temperature solid-state reaction. X-ray diffraction confirmed the successful formation of Na2Y2B2O7:Eu3+ phosphors with monoclinic phase. Under near-UV light (395 nm) excitation, Na2Y2B2O7:Eu3+ phosphors exhibited red emission around 619 nm due to the 5D0→7F2 transition. The intensity of the 5D0→7F2 transition increased with respect to Eu3+ ions concentration in Na2Y2(1-x)B2O7:xEu3+ (0.05 ≤ x ≤ 0.5) phosphors and the luminescence quenching was observed at x = 0.35. The critical distance (Rc) and θ were calculated to be 9.20 Å and 5.07, respectively, and thus the dipole-dipole interaction could play a significant role in concentration quenching. The lifetimes of the Na2Y2(1-x)B2O7:xEu3+ phosphors were calculated for various concentrations (x) of Eu3+ ions. In addition, the determined color purity of Na2Y2B2O7:0.35Eu3+ phosphor was 98.2% and internal quantum efficiency was 36.6%. Temperature-dependent photoluminescence study showed that emission intensity at 423 K was 40.2% of its initial at room temperature. The calculated activation energy of the Na2Y2B2O7:0.35Eu3+ phosphor was 0.16 eV. The above results strongly recommended that the Eu3+ ions activated Na2Y2B2O7 phosphors can be utilized for solid-state lighting technology such as phosphor converted white-light emitting diodes." @default.
- W2891530813 created "2018-09-27" @default.
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- W2891530813 date "2019-01-01" @default.
- W2891530813 modified "2023-10-18" @default.
- W2891530813 title "Synthesis, luminescence properties and thermal stability of Eu3+-activated Na2Y2B2O7 red phosphors excited by near-UV light for pc-WLEDs" @default.
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- W2891530813 doi "https://doi.org/10.1016/j.jlumin.2018.09.008" @default.
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