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• W2891531710 abstract "Star polymers are within the most topologically entangled macromolecules. For a star to move the current theory is that one arm must retract to the branch point. The probability of this event falls exponentially with molecular weight, and a quicker relaxation pathway eventually takes over. With a simulation over a hundred times faster than earlier studies, we demonstrate that the mean square displacement scales with a power law 1/16 in time, instead of the previously assumed zero. It suggests that star polymer motion is the result of two linear relaxations coinciding in time. By analogy to linear polymers, which reptate with a random walk embedded in a 3D network, we show that star polymers relax by a random walk in a 5D network." @default.
• W2891531710 created "2018-09-27" @default.
• W2891531710 creator A5024056256 @default.
• W2891531710 date "2018-09-13" @default.
• W2891531710 modified "2023-09-26" @default.
• W2891531710 title "5D Entanglement in Star Polymer Dynamics" @default.
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• W2891531710 doi "https://doi.org/10.1002/adts.201800078" @default.
• W2891531710 hasPublicationYear "2018" @default.
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