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• W2891536485 endingPage "15281" @default.
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• W2891536485 abstract "A doubly base-stabilised diborane based on a benzylphosphine linker was prepared by a salt elimination reaction between 2-LiC6 H4 CH2 PCy2 ⋅Et2 O and B2 Br4 . This compound was reduced with KC8 to its corresponding diborene, with the benzylphosphine forming a five-membered chelate. The diborene reacts with butadiene, 2-trimethylsiloxy-1,3-butadiene, and isoprene to form 4,5-diboracyclohexenes, which interconvert between their 1,1- (geminal) and 1,2- (vicinal) chelated isomers. The 1,1-chelated diborene undergoes a halide-catalysed isomerisation into its thermodynamically favoured 1,2-isomer, which undergoes Diels-Alder reactions more slowly than the kinetic product." @default.
• W2891536485 created "2018-09-27" @default.
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• W2891536485 date "2018-11-12" @default.
• W2891536485 modified "2023-09-29" @default.
• W2891536485 title "Chelated Diborenes and Their Inverse‐Electron‐Demand Diels–Alder Reactions with Dienes" @default.
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• W2891536485 doi "https://doi.org/10.1002/anie.201809217" @default.
• W2891536485 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30204298" @default.
• W2891536485 hasPublicationYear "2018" @default.
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