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- W2891552197 abstract "Poor stability has been one of the major difficulties affecting to the practical application of metal-organic frameworks (MOFs). In this work, we obtained two 3D structurally isomeric Cd-MOFs, {[Cd6(NH2Me2)2(PTB)4(HCOO)2(H2O)]·(DMF)13·(H2O)4} n (FJU-35) and {[Cd6(NH2Me2)2(PTB)4(HCOO)2]·(DMF)6·(H2O)2} n (FJU-36) (H3PTB = pyridine-2,4,6-tribenzoic acid) containing different CdII-O-CdII chains by varying the addition agents. FJU-35 with coordinated solvent and formate in asymmetric μ3-η1:η2 coordination mode within the CdII-O-CdII chains is vulnerable to external attacks and is apt to collapse after activation, while FJU-36 with no coordinated solvent in the CdII-O-CdII chains but fully protected by the carboxylates from the ligands and the symmetric formate in the coordination mode μ3-η2:η2 is stable, and its activated sample shows efficient separation of C2H2/CH4 and C2H2/CO2 mixtures. Conversely, FJU-35 with more vulnerability is more sensitive to the detection of nitrobenzene than FJU-36." @default.
- W2891552197 created "2018-09-27" @default.
- W2891552197 creator A5007794906 @default.
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- W2891552197 creator A5066215589 @default.
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- W2891552197 creator A5083000658 @default.
- W2891552197 date "2018-09-21" @default.
- W2891552197 modified "2023-10-06" @default.
- W2891552197 title "Robustness, Selective Gas Separation, and Nitrobenzene Sensing on Two Isomers of Cadmium Metal–Organic Frameworks Containing Various Metal–O–Metal Chains" @default.
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- W2891552197 doi "https://doi.org/10.1021/acs.inorgchem.8b02212" @default.
- W2891552197 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30240204" @default.
- W2891552197 hasPublicationYear "2018" @default.
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