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- W2891552263 abstract "CeO2–WO3–ZrO2 mixed oxides were prepared by the homogeneous precipitation method for the selective catalytic reduction of NOx with NH3 (NH3–SCR). The effects of hydrothermal aging on the catalytic performances of CeO2–WO3–ZrO2 were investigated. The results showed that CeO2–WO3–ZrO2 catalyst exhibited excellent NH3–SCR activity for removal of NOx and hydrothermal stability. After hydrothermal aging at 850 °C for 16 h, the optimum CeO2–WO3–ZrO2 catalyst could still realize 80% NOx conversion at 300–500 °C even under a high gas hourly space velocity of 250 000 h–1. The structural properties, redox ability, surface species, and acidity of fresh and hydrothermally aged CeO2–WO3–ZrO2 catalysts were characterized by N2-physisorption, XRD, Raman, H2-TPR, XPS, NH3-TPD, and in situ DRIFTS. The characterization results showed that decreases of 89% of the surface area and 71% of the NH3 storage capacity as well as new phase formation occurred for the CeO2–WO3–ZrO2 sample after hydrothermal aging at 850 °C for 16 h. The activity of hydrothermally aged CeO2–WO3–ZrO2 was mainly attributed to the retention of redox-acid sites and their interaction due to the formation of Ce–Zr solid solutions and Ce4W9O33." @default.
- W2891552263 created "2018-09-27" @default.
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- W2891552263 date "2018-10-08" @default.
- W2891552263 modified "2023-10-18" @default.
- W2891552263 title "Hydrothermal Stability of CeO<sub>2</sub>–WO<sub>3</sub>–ZrO<sub>2</sub> Mixed Oxides for Selective Catalytic Reduction of NOx by NH<sub>3</sub>" @default.
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- W2891552263 doi "https://doi.org/10.1021/acs.est.8b03732" @default.
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