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- W2891556535 abstract "The Cu2O-catalyzed reaction between equimolar amounts of easily available 3-substituted-2-bromo-2-propen-1-ols and dicyclohexyl carbodiimide in DMSO at 100 °C using K3PO4 as the base and in the absence of any additive exclusively delivers substituted 2-iminooxazolidines with yields up to 80%. The highly selective transformation is assumed to start with an intermolecular 1,2-addition, which is followed by an intramolecular N-vinylation. The products can also be obtained in the absence of Cu2O, albeit in lower yields." @default.
- W2891556535 created "2018-09-27" @default.
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- W2891556535 date "2018-11-01" @default.
- W2891556535 modified "2023-10-14" @default.
- W2891556535 title "Formation of substituted 2-iminooxazolidines via intermolecular 1,2-addition/intramolecular N-vinylation using 3-substituted-2-bromo-2-propen-1-ols as substrates" @default.
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- W2891556535 doi "https://doi.org/10.1016/j.tet.2018.08.051" @default.
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