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• W2891566487 abstract "Solid solutions Co 3– x Zn x TeO 6 ( x = 0–3) were prepared both in polycrystalline and single‐crystalline form using solid state reactions and chemical vapour transport reactions, respectively. Miscibility between the isotypic end members was established over the complete range ( C 2/ c, Z = 12, a ≈ 14.85, b ≈ 8.83, c ≈ 10.34 Å, β ≈ 93°). Crystal structure determinations, performed on basis of single crystal laboratory X‐ray (at 295 K) and synchrotron (at 10 and 100 K) data of Co 3 TeO 6 and selected solid solutions, revealed no structural phase transition and allowed a detailed insight into the Co → Zn substitution mechanism. The coordination polyhedra of the five crystallographically independent M 2+ cations are distorted octahedra (for three cations), one distorted tetrahedron and one distorted square pyramid. With increasing Zn content the polyhedral distortions increase, and the preference of the Zn 2+ cation for the tetrahedral coordination becomes distinctive. Optical absorption and diffuse reflectance spectroscopy reveal extraordinary strong crystal field absorption effects, over wide x ranges predominantly governed by Co 2+ in the single tetrahedral and one strongly acentric distorted octahedral site. Superposition Model crystal field calculations yield intrinsic and power‐law exponent parameters in general agreement with previous data for Co 2+ . The five cation sites show comparatively high crystal field strengths at generally very low interelectronic repulsion parameters, indicating prominent covalent contribution to Co–O bonding in Co 3– x Zn x TeO 6 solid solutions." @default.
• W2891566487 created "2018-09-27" @default.
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• W2891566487 date "2018-10-04" @default.
• W2891566487 modified "2023-09-25" @default.
• W2891566487 title "Crystal Chemistry, Optical Spectroscopy and Crystal Field Calculations of Co ₃ TeO ₆ and Solid Solutions Co _{3– <i>x</i>} Zn <i> _x </i> TeO ₆" @default.
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• W2891566487 doi "https://doi.org/10.1002/ejic.201800701" @default.
• W2891566487 hasPublicationYear "2018" @default.
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